Versatility of DABCO as a Reagent in Organic Synthesis: A Review

N Chakraborty, AK Mitra - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
DABCO (1, 4-diazabicyclo [2.2. 2] octane) has garnered a lot of interest for numerous
organic transformations since it is a low-cost, environmentally friendly, highly reactive …

Recent progress and prospects in the organocatalytic Morita–Baylis–Hillman reaction

M Maneesha, SH Haritha, T Aneeja, G Anilkumar - RSC advances, 2024 - pubs.rsc.org
The organocatalytic asymmetric Morita–Baylis–Hillman (MBH) reaction produces a
significant carbon–carbon bond formation that involves the addition of α, β-unsaturated …

Water sensitivity of heteroepitaxial Cu-MOF films: dissolution and re-crystallization of 3D-oriented MOF superstructures

LA Brandner, M Linares-Moreau, G Zhou… - Chemical …, 2023 - pubs.rsc.org
3D-oriented metal–organic framework (MOF) films and patterns have recently emerged as
promising platforms for sensing and photonic applications. These oriented polycrystalline …

Fuel acid drives base catalysis and supramolecular cage-to-device transformation under dissipative conditions

D Mondal, A Ghosh, I Paul, M Schmittel - Organic Letters, 2021 - ACS Publications
In State-I, a mixture comprising a DABCO-bridged tris (zinc-porphyrin) double decker and a
free biped (= slider), catalysis was OFF. Acid addition (TFA or Di-Stefano fuel acid) to State-I …

Renewable synthesis of novel acrylates from biomass‐derived 5‐substituted‐2‐furaldehydes by Morita‐Baylis‐Hillman reaction

HN Anchan, S Dutta - ChemistrySelect, 2023 - Wiley Online Library
Biomass‐derived furfurals are becoming increasingly popular as renewable chemical
building blocks for synthesizing specialty chemicals. Morita‐Baylis‐Hillman (MBH) reaction …

A surprise landing on the terra incognita of macrocyclic dibridgehead diorganoarsines: syntheses, structures, and reactivities

SR Zarcone, PJ Verardi, N Bhuvanesh… - Chemical …, 2022 - pubs.rsc.org
Reactions of trans-[Fe (CO) 2 (NO)(As ((CH2) n) 3As)]+ BF4−(n= 10, 12, 14) and Bu4N+ Cl−
afford the title compounds As ((CH2) n) 3As, which upon reaction (n= 14) with MCl2 (M= Pt …

Catalyst-and Base-Free Synthesis of Morita–Baylis–Hillman and Rauhut–Currier Adducts of β-Aminonitroalkenes

S Pednekar, ST Sivanandan, D Kumar… - The Journal of …, 2023 - ACS Publications
A facile, base-and catalyst-free synthesis of Morita–Baylis–Hillman and Rauhut–Currier
adducts of β-aminonitroalkenes with different electrophiles such as ethyl glyoxylate …

A perspective on environmentally benign protocols of thiazole synthesis

A Chowdhury, S Patel, A Sharma, A Das… - Chemistry of …, 2020 - Springer
Thiazole has widespread importance in materials and medicines. Several reviews are
reported which cover essential properties of thiazoles such as pharmacological activities …

DABCO as a potential catalyst for the CO2 fixation: A density functional theory and ab initio molecular dynamics study

M Faizan, R Pawar - Journal of Physical Organic Chemistry, 2022 - Wiley Online Library
Increasing concentration of CO2 in the atmosphere is a great concern today. One of the best
ways to overcome this challenge is to convert CO2 into useful chemicals. Referring to the …

Recent advances in the synthetic applications of Morita–Baylis–Hillman and Rauhut–Currier adducts of nitroalkenes

ST Sivanandan, DK Nair… - Organic & Biomolecular …, 2023 - pubs.rsc.org
The Morita–Baylis–Hillman (MBH) and Rauhut–Currier (RC) adducts of nitroalkenes are
important synthetic intermediates in organic synthesis. This review discusses the …