Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Controlled/living radical polymerization: Features, developments, and perspectives

WA Braunecker, K Matyjaszewski - Progress in polymer science, 2007 - Elsevier
Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

Nitroxide-mediated radical polymerization: limitations and versatility

RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

The strength of multi-scale modeling to unveil the complexity of radical polymerization

DR D'hooge, PHM Van Steenberge… - Progress in Polymer …, 2016 - Elsevier
The strength of multi-scale modeling to support the fundamental understanding and design
of radical polymerization processes is illustrated, considering both controlled and free …

Degradable polystyrene via the cleavable comonomer approach

N Gil, B Caron, D Siri, J Roche, S Hadiouch… - …, 2022 - ACS Publications
Polystyrene (PS) is a major commodity polymer widely used in various applications ranging
from packaging to insulation thanks to its low cost, high stiffness, and transparency as well …

Kinetic subtleties of nitroxide mediated polymerization

D Bertin, D Gigmes, SRA Marque… - Chemical Society Reviews, 2011 - pubs.rsc.org
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …

Toward nitroxide-mediated photopolymerization

Y Guillaneuf, D Bertin, D Gigmes, DL Versace… - …, 2010 - ACS Publications
A new alkoxyamine (methyl 2-((4-benzoylphenyl)((1-methoxy-2-methyl-1-oxopropan-2-yl)
oxy) amino)-2-methylpropanoate 4) bearing a chromophore group directly linked to the …

Thermally reprocessable bio-based polymethacrylate vitrimers and nanocomposites

F Hajiali, S Tajbakhsh, M Marić - Polymer, 2021 - Elsevier
Vitrimers are covalently cross-linked polymeric materials that can be processed upon
heating wherein triggerable polymer networks shuffle chemical bonds through exchange …