The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …
Gold-catalyzed multicomponent reactions
Multicomponent reactions (MCRs) have emerged as an important branch in organic
synthesis for the creation of complex molecular structures from more than two starting …
synthesis for the creation of complex molecular structures from more than two starting …
Chiral Hemilabile P, N‐Ligand‐Assisted Gold Redox Catalysis for Enantioselective Alkene Aminoarylation
Enantioselective, intermolecular alkene arylamination was achieved through gold redox
catalysis. Screening of ligands revealed chiral P, N ligands as the optimal choice, giving …
catalysis. Screening of ligands revealed chiral P, N ligands as the optimal choice, giving …
Oxidative additions of alkynyl/vinyl iodides to gold and gold-catalyzed vinylation reactions triggered by the MeDalphos ligand
J Rodriguez, A Tabey, S Mallet-Ladeira… - Chemical Science, 2021 - pubs.rsc.org
The hemilabile Ad2P (o-C6H4) NMe2 ligand promotes fast, quantitative and irreversible
oxidative addition of alkynyl and vinyl iodides to gold. The reaction is general. It works with a …
oxidative addition of alkynyl and vinyl iodides to gold. The reaction is general. It works with a …
Fundamental basis for implementing oxidant‐free Au (I)/Au (III) catalysis
Abstract Oxidant‐free Au (I)/Au (III) catalysis can still be regarded as a young and promising
chemistry. Because the first examples of gold catalysis were limited to the activation and …
chemistry. Because the first examples of gold catalysis were limited to the activation and …
Synthesis of silver and gold nanoparticles–enzyme–polymer conjugate hybrids as dual-activity catalysts for chemoenzymatic cascade reactions
Novel hybrids containing silver or gold nanoparticles have been synthesized in aqueous
media and at room temperature using enzymes or tailor–made enzyme–polymer …
media and at room temperature using enzymes or tailor–made enzyme–polymer …
Enantioselective C− H functionalization reactions under gold catalysis
Transition metal‐catalyzed enantioselective functionalization of ubiquitous C− H bonds has
proven to be promising field as it offers the construction of chiral molecular complexity in a …
proven to be promising field as it offers the construction of chiral molecular complexity in a …
Hemilabile MIC^ N ligands allow oxidant-free Au (i)/Au (iii) arylation-lactonization of γ-alkenoic acids
Oxidant-free Au-catalyzed reactions are emerging as a new synthetic tool for innovative
organic transformations. Oxidant-free Au-catalyzed reactions are emerging as a new …
organic transformations. Oxidant-free Au-catalyzed reactions are emerging as a new …
Asymmetric gold catalysis enabled by specially designed ligands
Over the past two decades, gold catalysis has witnessed a remarkable surge fueling the
advent of enantioselective gold catalysis. Based on the oxidation states of the gold complex …
advent of enantioselective gold catalysis. Based on the oxidation states of the gold complex …
Recent Advances in 1, 2‐Amino (hetero) arylation of Alkenes
Y Kwon, Q Wang - Chemistry–An Asian Journal, 2022 - Wiley Online Library
Alkene amino (hetero) arylation presents a highly efficient and straightforward strategy for
direct installation of amino groups and heteroaryl rings across a double bond …
direct installation of amino groups and heteroaryl rings across a double bond …