Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

The metallobiochemistry underlying the formation of the inorganic N–N-bond-containing
molecules nitrous oxide (N2O), dinitrogen (N2), and hydrazine (N2H4) is essential to the …

The metal–organic framework CuI-MFU-4 l reacts with NO, initially forming a copper (I)-
nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII …

Reduction of nitric oxide (NO) to nitrous oxide (N2O) is associated with immense biological
and health implications. Flavodiiron nitric oxide reductases (FNORs) are diiron containing …

Linkage isomers of reduced metal-nitrosyl complexes serve as key species in nitric oxide
(NO) reduction at monometallic sites to produce nitrous oxide (N2O), a potent greenhouse …

Herein, we review the preparation and coordination chemistry of cis and trans isomers of
hyponitrite,[N2O2] 2–. Hyponitrite is known to bind to metals via a variety of bonding modes …

A stepwise reduction sequence from nitrate to dinitrogen gas at a single nickel center was
discovered. A PNP nickel scaffold (PNP−= N [2-PiPr2-4-Me-C6H3] 2) emerged as a …

Transition-metal-mediated reductive coupling of nitric oxide (NO (g)) to nitrous oxide (N2O
(g)) has significance across the fields of industrial chemistry, biochemistry, medicine, and …

Reductive coupling of nitric oxide (NO) to give N2O is an important reaction in the global
nitrogen cycle. Here, a dinickel (II) dihydride complex 1 that releases H2 upon substrate …