An overview of recent analysis and detection of acetylcholine

X Gu, X Wang - Analytical Biochemistry, 2021 - Elsevier
Acetylcholine (ACh), the major neurotransmitter secreted by cholinergic neurons, is widely
found in the peripheral and central nervous systems, and its main function is to complete the …

Ethylene oligomerization on nickel catalysts on a solid acid support: From New mechanistic insights to tunable bifunctionality

E Koninckx, PSF Mendes, JW Thybaut… - Applied Catalysis A …, 2021 - Elsevier
Light alkene oligomerization on heterogeneous acidic catalysts is widely and successfully
used in current commercial processes. However, ethylene oligomerization remains …

Structure and site evolution of framework Ni species in MIL-127 MOFs for propylene oligomerization catalysis

B Yeh, S Chheda, SD Prinslow… - Journal of the …, 2023 - ACS Publications
A mixed-valence oxotrimer metal–organic framework (MOF), Ni-MIL-127, with a fully
coordinated nickel atom and two iron atoms in the inorganic node, generates a missing …

Solvent mediated interactions on alkene epoxidations in Ti-MFI: effects of solvent identity and silanol density

C Torres, DS Potts, DW Flaherty - ACS Catalysis, 2023 - ACS Publications
Selective alkene oxidation rates within zeolite pores reflect differences in contributions from
thermodynamic nonidealities introduced by noncovalent interactions at solid–liquid …

Theoretical Assessment of the Mechanism and Active Sites in Alkene Dimerization on Ni Monomers Grafted onto Aluminosilicates: (Ni–OH)+ Centers and C–C …

NR Jaegers, E Iglesia - Journal of the American Chemical Society, 2023 - ACS Publications
Ni-based solids are effective catalysts for alkene dimerization, but the nature of active
centers and identity and kinetic relevance of bound species and elementary reactions …

Direct analysis at temporal and molecular level of deactivating coke species formed on zeolite catalysts with diverse pore topologies

I Hita, HO Mohamed, Y Attada, N Zambrano… - Catalysis Science & …, 2023 - pubs.rsc.org
The mechanistic understanding of coke formation on zeolites is elusive, given the limitations
for the extraction and analysis of coke species. Here, we analyze the evolution of …

Thermostability promotion of α-diimine nickel precatalysts tailored with 2, 6-bis (bis (4-fluorophenyl) methyl)-3, 4, 5-trimethoxyaniline for PE elastomer synthesis

Z Hu, G Ren, Q Mahmood, Z Yu, Y Wang… - New Journal of …, 2024 - pubs.rsc.org
The influence of axial steric hindrance in α-diimine nickel catalysts on ethylene
polymerization is paramount for enhancing the catalytic performance especially in terms of …

Synthesis and catalytic behavior of nickel heterogenized in covalent organic frameworks as precatalysts in ethylene oligomerization

D Li, L Guo, F Li, J Huang, J Li, M Li, C Li - Microporous and Mesoporous …, 2022 - Elsevier
Two covalent organic frameworks (COFs), as the supports of transition metal catalysts, were
prepared and coordinated with nickel to synthesize two precatalysts for ethylene …

Validation of the Cossee–Arlman mechanism for propylene oligomerization on Ni/UiO-66

B Yeh, S Chheda, J Zheng, J Schmid… - Catalysis Science & …, 2023 - pubs.rsc.org
Steady state rate expressions can be derived to distinguish the Cossee–Arlman and
metallacycle mechanisms postulated for propylene oligomerization on nickel-based …

Dynamic interconversion of metal active site ensembles in zeolite catalysis

SH Krishna, CB Jones, R Gounder - Annual Review of …, 2021 - annualreviews.org
Catalysis science is founded on understanding the structure, number, and reactivity of active
sites. Kinetic models that consider active sites to be static and noninteracting entities are …