Over the past few years, the development of efficient methods to construct high‐valued N‐
heterocyclic molecules have received massive attention owing to their extensive application …

Skeletal editing involves making specific point‐changes to the core of a molecule through
the selective insertion, deletion or exchange of atoms. It thus represents a potentially …

Metalloradical catalysis (MRC) exploits the metal-centred radicals present in open-shell
metal complexes as one-electron catalysts for the generation of metal-stabilized organic …

Although they offer great potentials, the high reactivity and diverse pathways of radical
chemistry pose difficult problems for applications in organic synthesis. In addition to the …

Discovered as organometallic curiosities in the 1970s, carbene radicals have become a
staple in modern-day homogeneous catalysis. Carbene radicals exhibit nucleophilic radical …

A catalytic system for intermolecular benzylic C (sp3)–H amination is developed utilizing 1,
2, 3, 4-tetrazole as a nitrene precursor via iron catalysis. This method enables direct …

A concept for intermolecular C–N cross-coupling amination has been discovered using
tetrazoles and aromatic and aliphatic azides with boronic acids under iron-catalyzed …

Chiral benzylic amines are privileged motifs in pharmacologically active molecules.
Intramolecular enantioselective radical C (sp3)− H functionalization by hydrogen‐atom …

Direct conversion of hydrocarbons into amines represents an important and atom-economic
goal in chemistry for decades. However, intermolecular cross-coupling of terminal alkenes …

Since Friedrich Wöhler's groundbreaking synthesis of urea in 1828, organic synthesis over
the past two centuries has predominantly relied on the exploration and utilization of …