High-voltage liquid electrolytes for Li batteries: progress and perspectives

X Fan, C Wang - Chemical Society Reviews, 2021 - pubs.rsc.org
Since the advent of the Li ion batteries (LIBs), the energy density has been tripled, mainly
attributed to the increase of the electrode capacities. Now, the capacity of transition metal …

Thermal Stability and Outgassing Behaviors of High‐nickel Cathodes in Lithium‐ion Batteries

Z Cui, A Manthiram - Angewandte Chemie International Edition, 2023 - Wiley Online Library
LiNiO2‐based high‐nickel layered oxide cathodes are regarded as promising cathode
materials for high‐energy‐density automotive lithium batteries. Most of the attention thus far …

Hollow-core optical fibre sensors for operando Raman spectroscopy investigation of Li-ion battery liquid electrolytes

E Miele, WM Dose, I Manyakin, MH Frosz, Z Ruff… - Nature …, 2022 - nature.com
Improved analytical tools are urgently required to identify degradation and failure
mechanisms in Li-ion batteries. However, understanding and ultimately avoiding these …

Layered Cathode Materials for Lithium-Ion Batteries: Review of Computational Studies on LiNi1–xyCoxMnyO2 and LiNi1–xyCoxAlyO2

A Chakraborty, S Kunnikuruvan, S Kumar… - Chemistry of …, 2020 - ACS Publications
At present the most successful rechargeable battery is the Li-ion battery, due to the small
size, high energy density, and low reduction potential of Li. Computational materials science …

Rechargeable alkali-ion battery materials: theory and computation

A Van der Ven, Z Deng, S Banerjee, SP Ong - Chemical reviews, 2020 - ACS Publications
Since its development in the 1970s, the rechargeable alkali-ion battery has proven to be a
truly transformative technology, providing portable energy storage for devices ranging from …

In‐situ intermolecular interaction in composite polymer electrolyte for ultralong life quasi‐solid‐state lithium metal batteries

K He, SHS Cheng, J Hu, Y Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Solid‐state lithium metal batteries built with composite polymer electrolytes using cubic
garnets as active fillers are particularly attractive owing to their high energy density, easy …

A fluorinated cation introduces new interphasial chemistries to enable high-voltage lithium metal batteries

Q Liu, W Jiang, J Xu, Y Xu, Z Yang, DJ Yoo… - Nature …, 2023 - nature.com
Fluorides have been identified as a key ingredient in interphases supporting aggressive
battery chemistries. While the precursor for these fluorides must be pre-stored in electrolyte …

Face to face at the cathode electrolyte interphase: from interface features to interphase formation and dynamics

SP Kühn, K Edström, M Winter… - Advanced Materials …, 2022 - Wiley Online Library
Abstract Development of high‐performing lithium‐based batteries inevitably calls for a
profound understanding and elucidation of the reactivity at the electrode–liquid electrolyte …

Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy

Y Zhang, Y Katayama, R Tatara, L Giordano… - Energy & …, 2020 - pubs.rsc.org
Understanding (electro-) chemical reactions at the electrode–electrolyte interface (EEI) is
crucial to promote the cycle life of lithium-ion batteries. In this study, we developed an in situ …

Ni crossover catalysis: truth of hydrogen evolution in Ni-rich cathode-based lithium-ion batteries

X Wang, D Ren, H Liang, Y Song, H Huo… - Energy & …, 2023 - pubs.rsc.org
Hydrogen in Ni-rich cathode-based batteries is always accompanied by capacity decay and
safety risks. However, insights into the H2 evolution have puzzled the battery community for …