For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …

Relativistic effects are of major importance for understanding the properties of heavier atoms
and molecules. Volumes I-III of Relativistic Theory of Atoms and Molecules constitute the …

The fundamental vibrational modes of 11B2H6, 11B2D6, 10B2H6, and 10B2D6 have been
obtained from vibrational configuration interaction calculations including up to 6-tuple …

The vicinal frustrated P/B Lewis pair (FLP) Mes2PCH2CH2B (C6F5) 2 reacts with 9-
borabicyclo [3.3. 1] nonane (9-BBN) by C6F5vs. H exchange at boron to give the new [B]–H …

The indium phosphide (001) surface provides a unique chemical environment for studying
the reactivity of hydrogen toward the electron-deficient group IIIA element, indium. Hydrogen …

Both experimental and theoretical investigations are reported on the infrared spectrum of
vinylphosphine-borane (CH 2= CHPH 2⋅ BH 3)⁠, a donor-acceptor complex. The gas …

Interest in metal hydrides arises from the fact that they are sources of the corresponding
elements to generate layers of group III–V semiconductors. For this reason, hydrides such as …

Motivation. The recent matrix isolation infrared (IR) studies by Downs and co–workers
reported the detection of some indium subhydride In2H2 isomers. The dibridged isomer 1 …

DFT-B3LYP calculations have been carried out to assess the fate of the Pd/X group
intermolecular exchange in the [PdBr (PH3)(C6H5)(C6H5X)] system, where X is either H, an …

Tetraborane (10) is well known and 2-gallatetraborane (10) has been synthesized. Other
isomers of both systems along with gallaborane (10), digallatetraborane (10) and tri …