Multiscale CO2 Electrocatalysis to C2+ Products: Reaction Mechanisms, Catalyst Design, and Device Fabrication

T Yan, X Chen, L Kumari, J Lin, M Li, Q Fan… - Chemical …, 2023 - ACS Publications
Electrosynthesis of value-added chemicals, directly from CO2, could foster achievement of
carbon neutral through an alternative electrical approach to the energy-intensive …

A rational design of functional porous frameworks for electrocatalytic CO 2 reduction reaction

C Wang, Z Lv, W Yang, X Feng, B Wang - Chemical Society Reviews, 2023 - pubs.rsc.org
The electrocatalytic CO2 reduction reaction (ECO2RR) is considered one of the approaches
with the most potential to achieve lower carbon emissions in the future, but a huge gap still …

Hydrophobic, Ultrastable Cuδ+ for Robust CO2 Electroreduction to C2 Products at Ampere-Current Levels

M Fang, M Wang, Z Wang, Z Zhang… - Journal of the …, 2023 - ACS Publications
Copper (Cu) is the only known material that can efficiently electrocatalyze CO2 to value-
added multicarbon products. Owing to the instability of the Cuδ+ state and microscopic …

Asymmetric Low-Frequency Pulsed Strategy Enables Ultralong CO2 Reduction Stability and Controllable Product Selectivity

XD Zhang, T Liu, C Liu, DS Zheng… - Journal of the …, 2023 - ACS Publications
Copper-based catalysts are widely explored in electrochemical CO2 reduction (CO2RR)
because of their ability to convert CO2 into high-value-added multicarbon products …

Accelerating multielectron reduction at CuxO nanograins interfaces with controlled local electric field

W Guo, S Zhang, J Zhang, H Wu, Y Ma, Y Song… - Nature …, 2023 - nature.com
Regulating electron transport rate and ion concentrations in the local microenvironment of
active site can overcome the slow kinetics and unfavorable thermodynamics of CO2 …

Electrocatalytic CO2 reduction to alcohols by modulating the molecular geometry and Cu coordination in bicentric copper complexes

B Yang, L Chen, S Xue, H Sun, K Feng, Y Chen… - Nature …, 2022 - nature.com
Electrocatalytic reduction of CO2 into alcohols of high economic value offers a promising
route to realize resourceful CO2 utilization. In this study, we choose three model bicentric …

Recent Advances in Electrochemical, Photochemical, and Photoelectrochemical Reduction of CO2 to C2+ Products

GH Han, J Bang, G Park, S Choe, YJ Jang, HW Jang… - Small, 2023 - Wiley Online Library
Environmental problems such as global warming are one of the most prominent global
challenges. Researchers are investigating various methods for decreasing CO2 emissions …

Electrochemical CO2 Reduction over Copper Phthalocyanine Derived Catalysts with Enhanced Selectivity for Multicarbon Products

J Zhang, TH My Pham, Z Gao, M Li, Y Ko… - ACS …, 2023 - ACS Publications
Metal complexes have shown impressive selectivity and activity as catalysts for
electrochemical CO2 reduction (CO2RR), yet the nature of their active sites under operating …

A Porous π–π Stacking Framework with Dicopper(I) Sites and Adjacent Proton Relays for Electroreduction of CO2 to C2+ Products

HL Zhu, HY Chen, YX Han, ZH Zhao… - Journal of the …, 2022 - ACS Publications
Crystalline porous materials sustained by supramolecular interactions (eg, π–π stacking
interactions) are a type of molecular crystals showing considerable stability, but their …

Au-activated N motifs in non-coherent cupric porphyrin metal organic frameworks for promoting and stabilizing ethylene production

X Xie, X Zhang, M Xie, L Xiong, H Sun, Y Lu… - Nature …, 2022 - nature.com
Direct implementation of metal-organic frameworks as the catalyst for CO2 electroreduction
has been challenging due to issues such as poor conductivity, stability, and limited> 2e …