Transition metals have been an indispensable component of modern catalysis and among
these palladium is the top‐ranked choice of chemists as a catalyst. After the several …

The Pd/C-catalyzed reactions, including reduction reactions and cross-coupling reactions,
play an irreplaceable role in modern organic synthesis. Compared to the homogeneous …

A new technique for the ex situ generation of carbon monoxide (CO) and its efficient
incorporation in palladium catalyzed carbonylation reactions was achieved using a simple …

A simple, efficient and ligand-free protocol for the Suzuki–Miyaura reaction and base-free
Heck–Matsuda reactions under mild reaction conditions have been developed over …

Carbonylation reactions under transition metal catalysis have emerged as one of the most
important strategies for the construction of CO inserted molecules having both industrial and …

Polystyrene supported palladium (Pd@ PS) catalyzed cost-efficient and sustainable protocol
for carbonylative Suzuki-Miyaura cross-coupling (C-SMCC) reaction has been reported …

Carbonylation reactions with carbon monoxide (CO) provide efficient and attractive routes
for the synthesis of bulk and fine chemicals. However, the practice of using a large excess of …

This work reports oxidative N-dealkylation/carbonylation of tertiary amines to tertiary amides
by using molecular oxygen as a sole oxidant using a Pd/C catalyst. This protocol is free from …

This work reports the carbonylative Suzuki–Miyaura coupling of aryl iodides catalyzed by
palladacycles. More importantly, the palladacycles have been used to generate high …

While a ligand-free condition for Suzuki coupling reaction is desirable to minimize the
separation process of the final product, it adversely has affected a reaction kinetics. Herein …