Synthesis of Triazole-Linked Porous Cage Polymers: Modulating Cage Size for Tailored Iodine Adsorption

F Begar, M Erdogmus, Y Gecalp… - ACS Applied Polymer …, 2024 - ACS Publications
We present the synthesis of two triazole-linked porous cage polymers (pCAGEs) using two
D3h symmetric shape-persistent organic cages of different sizes as monomers. We …

Linking Nitrogen-Rich Pillar [5] arene to Hyper-Cross-Linked Polymers for Efficient and Simultaneous Capture of Iodine and Methyl Iodide

Q Zhang, TJ Yue, SJ Jiang, HM Guo - ACS Applied Polymer …, 2024 - ACS Publications
The simultaneous capture of radioactive molecular iodine (I2) and methyl iodide (CH3I)
coexisting in the exhaust stream of nuclear power plants has become an urgent and …

Triphenylamine [3] arenes: Streamlining Synthesis of a Versatile Macrocyclic Platform for Supramolecular Architectures and Functionalities

W Fang, J Zhang, M Guo, Y Zhao… - Angewandte Chemie …, 2024 - Wiley Online Library
Abstract Triphenylamine [3] arenes (TPA [3] s), featuring [16] paracyclophane backbone with
alternating carbon and nitrogen bridging atoms, were synthesized through a BF3⋅ Et2O …

Synthesis and Applications of Cage-Based Covalent Organic Frameworks

S Dutta, JI Hernández García, B Mishra… - Crystal Growth & …, 2024 - ACS Publications
Due to their unique structural characteristics, molecular cages have become pivotal
components in supramolecular chemistry and materials science. These cages possess the …