P-Stereogenic Phosphorus Ligands in Asymmetric Catalysis

T Imamoto - Chemical Reviews, 2024 - ACS Publications
Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Advances in the chemistry of tetrahydroquinolines

V Sridharan, PA Suryavanshi, JC Menendez - Chemical reviews, 2011 - ACS Publications
1.1. General Heterocyclic compounds, especially nitrogen heterocycles, are the most
important class of compounds in the pharmaceutical and agrochemical industries, with …

Asymmetric hydrogenation of nonaromatic cyclic substrates

Z Zhang, NA Butt, W Zhang - Chemical reviews, 2016 - ACS Publications
Chiral cyclic structures are found in numerous natural products, pharmaceutical compounds,
and important synthetic intermediates. Asymmetric hydrogenation, allowing for the …

Asymmetric hydrogenation of olefins using chiral crabtree-type catalysts: scope and limitations

JJ Verendel, O Pamies, M Dieguez… - Chemical …, 2014 - ACS Publications
The asymmetric hydrogenation of alkenes using transition metal catalysts continues to be a
growing field and a fundamental tool for organic synthetic chemists. In contrast to, for …

Chiral amine synthesis–recent developments and trends for enamide reduction, reductive amination, and imine reduction

TC Nugent, M El‐Shazly - Advanced Synthesis & Catalysis, 2010 - Wiley Online Library
The review examines the chiral amine literature from 2000–2009 (May) concerning
enantioselective and diastereoselective methods for N‐acylenamide and enamine …

Three-component enantioselective alkenylation of organophosphonates via nickel metallaphotoredox catalysis

X Li, M Yuan, F Chen, Z Huang, FL Qing, O Gutierrez… - Chem, 2023 - cell.com
The development of efficient catalytic multicomponent reactions (MCRs) is highly sought-
after in chemical synthesis. However, catalytic asymmetric MCRs, particularly involving …

Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs

P Etayo, A Vidal-Ferran - Chemical Society Reviews, 2013 - pubs.rsc.org
During the last few decades, rhodium-catalysed asymmetric hydrogenation of diverse
alkene classes has emerged as a powerful synthetic tool in the pharmaceutical industry …

Chiral chemistry of metal–camphorate frameworks

ZG Gu, C Zhan, J Zhang, X Bu - Chemical Society Reviews, 2016 - pubs.rsc.org
This critical review presents the various synthetic approaches and chiral chemistry of metal–
camphorate frameworks (MCamFs), which are homochiral metal–organic frameworks …

Cobalt precursors for high-throughput discovery of base metal asymmetric alkene hydrogenation catalysts

MR Friedfeld, M Shevlin, JM Hoyt, SW Krska, MT Tudge… - Science, 2013 - science.org
Asymmetric hydrogenation of alkenes is one of the most widely used methods for the
preparation of single enantiomer compounds, especially in the pharmaceutical and …

Chiral NHC–metal-based asymmetric catalysis

F Wang, L Liu, W Wang, S Li, M Shi - Coordination Chemistry Reviews, 2012 - Elsevier
The strong σ-donor but poor π-acceptor abilities of N-heterocyclic carbenes (NHCs) result in
chemical stability and coordination versatility, thus allowing them to coordinate with many …