Chiral metal–organic frameworks based on asymmetric synthetic strategies and applications

Z Sharifzadeh, K Berijani, A Morsali - Coordination Chemistry Reviews, 2021 - Elsevier
Chiral metal–organic frameworks (CMOFs) are a major part of chiral inorganic–organic
hybrid materials that lead to considerable attention of researchers, especially in recent …

Synthetic strategies towards chiral coordination polymers

HM Tay, N Kyratzis, S Thoonen, SA Boer… - Coordination Chemistry …, 2021 - Elsevier
Chiral coordination polymers and porous chiral MOFs have great potential as agents for
enantioselective separations, sensing, and catalysis due to their well-structured internal …

Highly enantioselective Friedel–Crafts alkylation of N, N-dialkylanilines with trans-β-nitrostyrene catalyzed by a homochiral metal–organic framework

K Tanaka, K Sakuragi, H Ozaki, Y Takada - Chemical Communications, 2018 - pubs.rsc.org
The first enantioselective Friedel–Crafts alkylation of N, N-dialkylanilines with trans-β-
nitrostyrene catalyzed by a homochiral metal–organic framework constructed from (R)-2, 2 …

Enantioselective Diels–Alder reaction in the confined space of homochiral metal–organic frameworks

K Tanaka, S Nagase, T Anami, M Wierzbicki… - RSC …, 2016 - pubs.rsc.org
A novel homochiral porous metal–organic framework (MOF) has been synthesized using (R)-
2, 2′-dihydroxy-1, 1′-binaphthyl-4, 4′-dibenzoic acid as the chiral ligand. This MOF acts …

Efficient HPLC enantiomer separation using a pillared homochiral metal–organic framework as a novel chiral stationary phase

K Tanaka, N Hotta, S Nagase, K Yoza - New Journal of Chemistry, 2016 - pubs.rsc.org
Efficient HPLC enantiomer separation using a pillared homochiral metal–organic framework
as a novel chiral stationary phase - New Journal of Chemistry (RSC Publishing) DOI:10.1039/C6NJ00090H …

Asymmetric ring-opening reaction of meso-epoxides with aromatic amines using homochiral metal–organic frameworks as recyclable heterogeneous catalysts

K Tanaka, M Kinoshita, J Kayahara, Y Uebayashi… - RSC …, 2018 - pubs.rsc.org
An efficient asymmetric ring-opening (ARO) reaction of meso-epoxides with aromatic amines
catalysed by a series of homochiral metal–organic frameworks (MOFs) was carried out …

Integration of a semi-rigid proline ligand and 4, 4′-bipyridine in the synthesis of homochiral metal–organic frameworks with helices

ZX Xu, Y Kang, ML Han, DS Li, J Zhang - Dalton Transactions, 2015 - pubs.rsc.org
A pair of 3-D homochiral metal–organic frameworks (HMOFs) based on a mixed semi-rigid 5-
(2-carboxypyrrolidine-1-carbonyl) isophthalate (PIA) ligand and rigid 4, 4′-bipyridine …

Acid‐Catalyzed Diastereoselective Reactions Inside MOF Pores

HG Baldoví, S Navalón… - Catalysis in Confined …, 2024 - Wiley Online Library
In this chapter we discuss the use of achiral metal‐organic frameworks (MOFs) as porous
heterogeneous catalysts for diastereoselective transformations. The list of selected …

Synthesis and Characterization of Chiral Metal-Organic Frameworks for Stereoselective Applications

M Sartor - 2015 - ediss.sub.uni-hamburg.de
A new isoreticular series of metal-organic frameworks, called UHM-25 (UHM: University of
Hamburg Materials), based on the copper paddle wheel motif and a novel set of homochiral …

[引用][C] Insights in Homochiral Metal-Organic Frameworks: From Their Synthesis to Enantioselective Applications

J Cabezas Giménez - Universitat Rovira i Virgili