Recent progress in the science of complex coacervation

CE Sing, SL Perry - Soft Matter, 2020 - pubs.rsc.org
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …

Complex coacervate‐based materials for biomedicine

WC Blocher, SL Perry - Wiley Interdisciplinary Reviews …, 2017 - Wiley Online Library
There has been increasing interest in complex coacervates for deriving and transporting
biomaterials. Complex coacervates are a dense, polyelectrolyte‐rich liquid that results from …

Phase behavior and salt partitioning in polyelectrolyte complex coacervates

L Li, S Srivastava, M Andreev, AB Marciel… - …, 2018 - ACS Publications
Polyelectrolyte complexes are omnipresent both in nature and in the technological world,
including nucleotide condensates, biological marine adhesives, food stabilizers …

RNA-based coacervates as a model for membraneless organelles: formation, properties, and interfacial liposome assembly

WM Aumiller Jr, F Pir Cakmak, BW Davis, CD Keating - Langmuir, 2016 - ACS Publications
Liquid–liquid phase separation is responsible for formation of P granules, nucleoli, and
other membraneless subcellular organelles composed of RNA and proteins. Efforts to …

Ion-pairing strength in polyelectrolyte complexes

J Fu, HM Fares, JB Schlenoff - Macromolecules, 2017 - ACS Publications
Polyelectrolyte complexes, PECs, are spontaneously formed blends of polyelectrolytes
bearing positive, Pol+, and negative, Pol–, repeat units. Many interesting PEC morphologies …

Polyelectrolyte complexes: Bulk phases and colloidal systems

J Van der Gucht, E Spruijt, M Lemmers… - Journal of colloid and …, 2011 - Elsevier
When aqueous solutions of polycations and polyanions are mixed, polyelectrolyte
complexes form. These are usually insoluble in water, so that they separate out as a new …

Oligonucleotide–peptide complexes: phase control by hybridization

JR Vieregg, M Lueckheide, AB Marciel… - Journal of the …, 2018 - ACS Publications
When oppositely charged polymers are mixed, counterion release drives phase separation;
understanding this process is a key unsolved problem in polymer science and biophysical …

Intermolecular interactions in polyelectrolyte and surfactant complexes in solution

N Khan, B Brettmann - Polymers, 2018 - mdpi.com
Polyelectrolytes are an important class of polymeric materials and are increasingly used in
complex industrial formulations. A core use of these materials is in mixtures with surfactants …

Driving forces of the complex formation between highly charged disordered proteins

A Chowdhury, A Borgia, S Ghosh… - Proceedings of the …, 2023 - National Acad Sciences
Highly disordered complexes between oppositely charged intrinsically disordered proteins
present a new paradigm of biomolecular interactions. Here, we investigate the driving forces …

Complexation and coacervation of polyelectrolytes with oppositely charged colloids

E Kizilay, AB Kayitmazer, PL Dubin - Advances in colloid and interface …, 2011 - Elsevier
Polyelectrolyte-colloid coacervation could be viewed as a sub-category of complex
coacervation, but is unique in (1) retaining the structure and properties of the colloid, and (2) …