Mechanically responsive molecular crystals

P Naumov, S Chizhik, MK Panda, NK Nath… - Chemical …, 2015 - ACS Publications
Transformation of energy into motion (work) is one of the basic processes of energy
conversion in nature. The processes of actuation underlying the transduction of light …

Crystals on the move: mechanical effects in dynamic solids

P Commins, IT Desta, DP Karothu, MK Panda… - Chemical …, 2016 - pubs.rsc.org
When exposed to external stimuli such as heat or light, certain single crystals can acquire
momentum and undergo motion. On a molecular scale, the motility of such dynamic single …

Engineering photomechanical molecular crystals to achieve extraordinary expansion based on solid-state [2+ 2] photocycloaddition

TY Xu, F Tong, H Xu, MQ Wang, H Tian… - Journal of the American …, 2022 - ACS Publications
Photomechanical molecular crystals are promising candidates for photoactuators and can
potentially be implemented as smart materials in various fields. Here, we synthesized a new …

Organic radical ferroelectric crystals with martensitic phase transition

N Zhang, W Sun, Y Zhang, HH Jiang, RG Xiong… - Nature …, 2023 - nature.com
Organic martensitic compounds are an emerging type of smart material with intriguing
physical properties including thermosalient effect, ferroelasticity, and shape memory effect …

Manipulating light‐induced dynamic macro‐movement and static photonic properties within 1D isostructural hydrogen‐bonded molecular cocrystals

S Li, B Lu, X Fang, D Yan - Angewandte Chemie International …, 2020 - Wiley Online Library
Smart molecular crystals with light‐driven mechanical responses have received interest
owing to their potential uses in molecular machines, artificial muscles, and biomimetics …

 Collective photothermal bending of flexible organic crystals modified with MXene-polymer multilayers as optical waveguide arrays

X Yang, L Lan, L Li, J Yu, X Liu, Y Tao, QH Yang… - Nature …, 2023 - nature.com
The performance of any engineering material is naturally limited by its structure, and while
each material suffers from one or multiple shortcomings when considered for a particular …

Mechanical effects of elastic crystals driven by natural sunlight and force

J Peng, C Han, X Zhang, J Jia, J Bai… - Angewandte Chemie …, 2023 - Wiley Online Library
Flexible crystals that can capture solar energy and convert it into mechanical energy are
promising for a wide range of applications such as information storage and actuators, but …

Bending, curling, rolling, and salient behavior of molecular crystals driven by [2+ 2] cycloaddition of a styrylbenzoxazole derivative

H Wang, P Chen, Z Wu, J Zhao… - Angewandte Chemie …, 2017 - Wiley Online Library
We report interesting photomechanical behaviors of the dynamic molecular crystals of (E)‐2‐
(2, 4‐dichlorostyryl) benzo [d] oxazole (BOACl24). The photosalient effect of the rod‐like …

Smart dynamic hybrid membranes with self-cleaning capability

E Pantuso, E Ahmed, E Fontananova, A Brunetti… - Nature …, 2023 - nature.com
The growing freshwater scarcity has caused increased use of membrane desalination of
seawater as a relatively sustainable technology that promises to provide long-term solution …

Shape-memory and self-healing effects in mechanosalient molecular crystals

DP Karothu, J Weston, IT Desta… - Journal of the American …, 2016 - ACS Publications
The thermosalient crystals of terephthalic acid are extraordinarily mechanically compliant
and reversibly shape-shift between two forms with different crystal habits. While the …