Synthesis and Suzuki–Miyaura cross-coupling of alkyl amine-boranes. A boryl radical-enabled Strategy

CS Buettner, C Stavagna, MJ Tilby… - Journal of the …, 2024 - ACS Publications
Alkyl organoborons are powerful materials for the construction of C (sp 3)–C (sp 2) bonds,
predominantly via Suzuki–Miyaura cross-coupling. These species are generally assembled …

Mechanistic Analysis Reveals Key Role of Interchalcogen Multicatalysis in Photo‐Aerobic 3‐Pyrroline Syntheses by Aza‐Wacker Cyclizations

S Graf, H Pesch, T Appleson, T Lei, A Breder… - …, 2024 - Wiley Online Library
A light‐driven dual and ternary catalytic aza‐Wacker protocol for the construction of 3‐
pyrrolines by partially disulfide‐assisted selenium‐π‐acid multicatalysis is reported. A …

[HTML][HTML] α-(Aminomethyl) acrylates as acceptors in radical–polar crossover 1, 4-additions of dialkylzincs: insights into enolate formation and trapping

A Palillero-Cisneros… - Beilstein Journal of …, 2023 - beilstein-journals.org
We demonstrate that α-(aminomethyl) acrylates are suitable acceptors for 1, 4-additions of
dialkylzincs in aerobic conditions. The air-promoted radical–polar crossover process …