The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

The efficient utilization of triplet excitons serves as a key driver for the advancement of
luminescence materials. Therefore, coordination compounds based on phosphorescence …

The photoluminescence of metal nanoclusters is typically low, and phosphorescence
emission is rare due to ultrafast free-electron dynamics and quenching by phonons. Here …

Metal clusters are useful phosphors, but highly luminescent examples are quite rare.
Usually, the phosphorescence of metal clusters is hindered by ambient O2 molecules …

Abstract A gold (I)‐cluster‐based twin‐cage has been constructed by post‐clustering
covalent modification of a hexa‐aldehyde cluster precursor with triaminotriethylamines. The …

Luminescent metal–organic cages are of great interest in contemporary research; however,
their designed synthesis remains challenging. Here, we created metal-cluster-derived …

The generation of two types of complexes with different topological connections and
completely different structural types merely via the substitution effect is extremely rare …

Self-assembly of three-dimensional (3D) metallosupramolecular cages has drawn
increasing attention for their potential to interconvert between different architectures due to …

Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …

Two different organometallic gold (I) compounds containing naphthalene and phenanthrene
as fluorophores and 2-pyridyldiphenylphosphane as the ancillary ligand were synthesized …