Direct Synthesis of Formamide from CO2 and H2O with Nickel–Iron Nitride Heterostructures under Mild Hydrothermal Conditions

T Beyazay, WF Martin, H Tuysuz - Journal of the American …, 2023 - ACS Publications
Formamide can serve as a key building block for the synthesis of organic molecules relevant
to premetabolic processes. Natural pathways for its synthesis from CO2 under early earth …

Amorphous Fe0.7Cu0.3Ox as a Bifunctional Catalyst for Selective Hydration of Nitriles to Amides in Water

T Fan, J Qin, X Du, F Yuan, H Zhao… - ACS Sustainable …, 2024 - ACS Publications
The development of sustainable and economical catalytic systems for the hydration of
nitriles into amides is of great industrial significance. In this work, amorphous Fe0. 7Cu0. 3O …

RNA-directed Peptide synthesis across a nicked loop

M Su, SJ Roberts, JD Sutherland - Nucleic Acids Research, 2024 - academic.oup.com
Ribosomal translation at the origin of life requires controlled aminoacylation to produce
mono-aminoacyl esters of tRNAs. Herein, we show that transient annealing of short RNA …

Contemporary Applications of Thioamides and Methods for their Synthesis

TN Hansen, CA Olsen - Chemistry–A European Journal, 2024 - Wiley Online Library
Thioamides are naturally occurring isosteres of amide bonds in which the chalcogen atom of
the carbonyl is changed from oxygen to sulfur. This substitution gives rise to altered …

UV Transmission in Prebiotic Environments on Early Earth

ZR Todd, GG Lozano, CL Kufner, S Ranjan… - Astrobiology, 2024 - liebertpub.com
Ultraviolet (UV) light is likely to have played important roles in surficial origins of life
scenarios, potentially as a productive source of energy and molecular activation, as a …

Multivacant polyoxometalate-stabilizing palladium nanoparticles catalyze the N-formylation of amines with CO 2 and H 2

W Lai, Y Jiang, H Liao, X Wei, Z Xu, J Ding… - New Journal of …, 2024 - pubs.rsc.org
In this work, the Keggin-type tri-and mono-palladium-substituted silicotungstates (POMs)
were constructed by the reaction of tri-and monovacant silicotungstates ([SiW9O34] 10− or …

[HTML][HTML] Light-Assisted Formation of Nucleosides and Nucleotides from Formamide in the Presence of Cerium Phosphate

S Gilboa, L Panz, N Arbell, Y Paz - Life, 2024 - mdpi.com
The abiotic formation of nucleotides from small, simple molecules is of large interest in the
context of elucidating the origin of life scenario. In what follows, it is shown that nucleosides …

Carbon‐and Nitrogen‐Based Complexes as Photocatalysts for Prebiotic and Oxygen Chemistry during Earth Evolution

Y Wang, H Wang, S Wang, Y Fang - … Chemie International Edition - Wiley Online Library
Sunlight has long served as primary energy source on our planet, shaping the behavior of
living organisms. Extensive research has been dedicated to unraveling the evolutionary …

Cerium Phosphate-Assisted Formation of Nucleosides and Nucleotides from Formamide in a One-Pot (Photo) catalytic Reaction

S Gilboa, L Panz, N Arbell, Y Paz - 2023 - chemrxiv.org
The abiotic formation of nucleotides from small, simple molecules is of large interest in the
context of elucidating the origin of life scenario. In what follows it is shown that nucleosides …

[PDF][PDF] The Network of Replication, Transcription, and Reverse Transcription of a Synthetic Genetic Cassette

H Yang, E Eremeeva, M Abramov… - Angewandte Chemie …, 2021 - lirias.kuleuven.be
Synthetic nucleic acids, with four non-canonical nucleobases, can function as genetic
materials. A comprehensive analysis of PCR amplification, transcription, reverse …