Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

This Review summarizes advances in fluorination by C (sp2)− H and C (sp3)− H activation.
Transition‐metal‐catalyzed approaches championed by palladium have allowed the …

An isolated Csingle bondH bond in a molecule has a very low reactivity owing to the large
kinetic barrier associated to the Csingle bondH bond cleavage and the apolar nature of this …

The development of methods for the direct conversion of carbonshydrogen bonds into
carbon-oxygen, carbon-halogen, carbon-nitrogen, carbon-sulfur, and carbon-carbon bonds …

Palladium-catalyzed C H activation/C O bond-forming reactions have emerged as
attractive tools for organic synthesis. Typically, these reactions require strong chemical …

Transition metals can assemble to form multinuclear complexes by engaging in direct metal-
to-metal interactions. Metal–metal covalent bonds provide a large perturbation in electronic …

C H oxidation has a long history and an ongoing presence in research at the forefront of
chemistry and interrelated fields. As such, numerous highly useful articles and reviews have …

The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

Pick your Pd partners: A number of catalytic systems have been developed for palladium‐
catalyzed C H activation/C C bond formation. Recent studies concerning the palladium …