Arylglyoxals in synthesis of heterocyclic compounds

B Eftekhari-Sis, M Zirak, A Akbari - Chemical reviews, 2013 - ACS Publications
Heterocycles are an extraordinarily important class of compounds, making up more than half
of all known organic compounds. Heterocycles are present in a wide variety of drugs, most …

Catalytic, asymmetric reactions of ketenes and ketene enolates

DH Paull, A Weatherwax, T Lectka - Tetrahedron, 2009 - Elsevier
For over a century, ketenes have intrigued organic chemists with their unusual physical
properties and unique spectrum of chemical reactivity; it is not an exaggeration to say that …

Pd-catalyzed carbonylation of diazo compounds at atmospheric pressure: a catalytic approach to ketenes

Z Zhang, Y Liu, L Ling, Y Li, Y Dong… - Journal of the …, 2011 - ACS Publications
The carbonylation of carbenes through catalytic cycles is highly desirable due to the
importance of ketene-mediated reactions in organic synthesis. In this investigation, a highly …

Meeting the Challenge of Intermolecular Gold (I)‐Catalyzed Cycloadditions of Alkynes and Allenes

ME Muratore, A Homs, C Obradors… - Chemistry–An Asian …, 2014 - Wiley Online Library
The development of gold (I)‐catalyzed intermolecular carbo‐and hetero‐cycloadditions of
alkynes and allenes has been more challenging than their intramolecular counterparts. Here …

Cyclic imines–preparation and application in synthesis

J Iwanejko, E Wojaczyńska - Organic & Biomolecular Chemistry, 2018 - pubs.rsc.org
The chemistry of cyclic imines has been gaining importance in the last decade because of
their broad spectrum of applications and biological importance. This review focuses on the …

Metal-free visible light-induced cross-dehydrogenative coupling of benzocyclic imines with water/P (O) H compounds: efficient access to functionalized benzazepines …

Z Fu, L Feng, Y Qin, X Mu, X Zhong, Z Wang… - Organic Chemistry …, 2024 - pubs.rsc.org
Visible light-induced cross-dehydrogenative coupling is a general and highly efficient
protocol for the synthesis of functionalized benzazepines/ones in a one-pot fashion, and is …

Tetrazole Diversification of Amino Acids and Peptides via Silver‐Catalyzed Intermolecular Cycloaddition with Aryldiazonium Salts

XY Liu, YL Yang, Y Dang, I Marek… - Angewandte …, 2023 - Wiley Online Library
Selective structural modification of amino acids and peptides is a central strategy in organic
chemistry, chemical biology but also in pharmacology and material science. In this context …

Aryne and CO 2-based formal [2+ 2+ 2] annulation to access tetrahydroisoquinoline-fused benzoxazinones

S Liu, K Zhang, Y Meng, J Xu, N Chen - Organic & Biomolecular …, 2023 - pubs.rsc.org
Tetrahydroisoquinoline and its fused polyheterocycles are prevalent structural motifs found
in numerous natural products. In this study, we report a highly efficient and convergent …

Gold-catalyzed intermolecular reactions of propiolic acids with alkenes:[4+ 2] annulation and enyne cross metathesis

HS Yeom, J Koo, HS Park, Y Wang… - Journal of the …, 2012 - ACS Publications
A gold-catalyzed intermolecular reaction of propiolic acids with alkenes led to a [4+ 2]
annulation or enyne cross metathesis. The [4+ 2] annulation proceeds with net cis-addition …

Synthesis of polysubstituted pyridines via a one-pot metal-free strategy

H Wei, Y Li, K Xiao, B Cheng, H Wang, L Hu… - Organic letters, 2015 - ACS Publications
An efficient strategy for the one-pot synthesis of polysubstituted pyridines via a cascade
reaction from aldehydes, phosphorus ylides, and propargyl azide is reported. The reaction …