Insights into polymer crystallization and melting from fast scanning chip calorimetry

A Toda, R Androsch, C Schick - Polymer, 2016 - Elsevier
Fast scanning chip calorimetry in its non-adiabatic version allows for heating and cooling at
rates up to 10 6 K s− 1, covering all polymer processing relevant rates. Furthermore it allows …

[PDF][PDF] Characterization of polymer crystallization kinetics via fast-scanning chip-calorimetry

YC He, KF Xie, YH Wang, DS Zhou… - Acta. Phys.-Chim. Sin, 2020 - whxb.pku.edu.cn
Understanding the crystallization behavior of polymers is a hot topic of study in polymer
processing because polymer components and their processing conditions control the …

Glass transition, crystallization of glass-forming melts, and entropy

JWP Schmelzer, TV Tropin - Entropy, 2018 - mdpi.com
A critical analysis of possible (including some newly proposed) definitions of the vitreous
state and the glass transition is performed and an overview of kinetic criteria of vitrification is …

Relaxation and crystal nucleation in polymer glasses

R Androsch, E Zhuravlev, JWP Schmelzer… - European Polymer …, 2018 - Elsevier
Depending on the degree of undercooling, polymers crystallize from heterogeneous or
homogeneous nuclei. The volume density of homogeneous nuclei at deep undercooling is …

Glass-forming tendency of molecular liquids and the strength of the intermolecular attractions

K Koperwas, K Adrjanowicz, Z Wojnarowska… - Scientific Reports, 2016 - nature.com
When we cool down a liquid below the melting temperature, it can either crystallize or
become supercooled, and then form a disordered solid called glass. Understanding what …

Crystallization of Cristobalite in Sodium Borosilicate Glass in the Presence of Cr2O3

M Konon, IG Polyakova, AS Mazur, AS Saratovskii… - Materials, 2023 - mdpi.com
Glass containing chromium is a promising material for use in various modern fields of
application (laser technology, optoelectronic devices, and luminescent resources) …

Crystallization of glass: What we know, what we need to know

JWP Schmelzer, VM Fokin… - International Journal of …, 2016 - Wiley Online Library
The relevance of the concepts of fragility and of the glass transition temperature for the
understanding of crystal nucleation and growth in glass‐forming liquids is explored. It is …

Kauzmann paradox and the crystallization of glass-forming melts

JWP Schmelzer, AS Abyzov, VM Fokin… - Journal of Non-Crystalline …, 2018 - Elsevier
General relations for the dependence of the thermodynamic driving force of crystallization
and the specific interfacial energy melt-crystal of critical crystal clusters on temperature and …

Crystallization of glass-forming melts: New answers to old questions

JWP Schmelzer, AS Abyzov - Journal of Non-Crystalline Solids, 2018 - Elsevier
In classical nucleation theory, the thermodynamic driving force of crystallization is computed
by comparing the bulk properties of the liquid and crystal phases for the respective …

Kinetic criteria of glass-formation, pressure dependence of the glass-transition temperature, and the Prigogine–Defay ratio

JWP Schmelzer, TV Tropin - Journal of Non-Crystalline Solids, 2015 - Elsevier
An analysis of some current topics of discussion in the theoretical modeling of the glass
transition and of glass properties is given. In the first part, a general model-independent …