N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces

M Koy, P Bellotti, M Das, F Glorius - Nature Catalysis, 2021 - nature.com
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …

N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

N-heterocyclic carbene-functionalized magic-number gold nanoclusters

MR Narouz, KM Osten, PJ Unsworth, RWY Man… - Nature …, 2019 - nature.com
Magic-number gold nanoclusters are atomically precise nanomaterials that have enabled
unprecedented insight into structure–property relationships in nanoscience. Thiolates are …

What does nanoparticle stability mean?

HT Phan, AJ Haes - The Journal of Physical Chemistry C, 2019 - ACS Publications
The term “nanoparticle stability” is widely used to describe the preservation of a particular
nanostructure property ranging from aggregation, composition, crystallinity, shape, size, and …

Surface chemistry of gold nanoparticles for health-related applications

J Zhang, L Mou, X Jiang - Chemical Science, 2020 - pubs.rsc.org
Functionalization of gold nanoparticles is crucial for the effective utilization of these materials
in health-related applications. Health-related applications of gold nanoparticles rely on the …

Au and Au-Based nanomaterials: Synthesis and recent progress in electrochemical sensor applications

T Xiao, J Huang, D Wang, T Meng, X Yang - Talanta, 2020 - Elsevier
This review summarizes the synthesis of gold (Au) and Au-based nanomaterials and their
recent advances of application in electrochemical small-molecule sensors, DNA sensors …

N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters

H Shen, G Tian, Z Xu, L Wang, Q Wu, Y Zhang… - Coordination Chemistry …, 2022 - Elsevier
N-heterocyclic carbenes (NHCs) represent one of the most important organic ligands in
coordination chemistry, and have been recently attracting increasing attention in …

Fundamentals and applications of N-heterocyclic carbene functionalized gold surfaces and nanoparticles

G Kaur, RL Thimes, JP Camden… - Chemical …, 2022 - pubs.rsc.org
The discovery of N-heterocyclic carbenes (NHCs) revolutionized organometallic chemistry
due to their strong metal–ligand bonds. These strong bonds also lend enhanced stability to …

N‐Heterocyclic Carbene‐Stabilized Ultrasmall Gold Nanoclusters in a Metal‐Organic Framework for Photocatalytic CO2 Reduction

Y Jiang, Y Yu, X Zhang, M Weinert… - Angewandte Chemie …, 2021 - Wiley Online Library
Abstract Ultrafine gold nanoclusters (Au‐NCs) are susceptible to migrate and aggregate,
even in the porosity of many crystalline solids. N‐heterocyclic carbenes (NHCs) are a class …

Highly Robust but Surface‐Active: An N‐Heterocyclic Carbene‐Stabilized Au25 Nanocluster

H Shen, G Deng, S Kaappa, T Tan, YZ Han… - Angewandte …, 2019 - Wiley Online Library
Surface organic ligands play a critical role in stabilizing atomically precise metal
nanoclusters in solutions. However, it is still challenging to prepare highly robust ligated …