Metal stereogenicity in asymmetric transition metal catalysis
PS Steinlandt, L Zhang, E Meggers - Chemical Reviews, 2023 - ACS Publications
Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …
stereocenters in organic synthesis, with the metal center providing a strong chemical …
Biomimetic asymmetric catalysis
X Xiao, K Xu, ZH Gao, ZH Zhu, C Ye, B Zhao… - Science China …, 2023 - Springer
Enzymes are the core for biological transformations in nature. Their structures and functions
have drawn enormous attention from biologists as well as chemists since last century. The …
have drawn enormous attention from biologists as well as chemists since last century. The …
Rational design of bioinspired catalysts for selective oxidations
Recognizing Nature's unique ability to perform challenging oxygenation reactions with
exquisite selectivity parameters at iron-dependent oxygenases, chemists have long sought …
exquisite selectivity parameters at iron-dependent oxygenases, chemists have long sought …
Catalytic asymmetric oxidation of amines to hydroxylamines
G Wang, T Chen, K Jia, W Ma, CH Tung… - Journal of the American …, 2023 - ACS Publications
Chiral hydroxylamines are increasingly common structural elements in pharmaceuticals and
agrochemicals, but their asymmetric synthesis remains challenging. Although …
agrochemicals, but their asymmetric synthesis remains challenging. Although …
Carbon Vacancy Mediated Incorporation of Ti3C2 Quantum Dots in a 3D Inverse Opal gC3N4 Schottky Junction Catalyst for Photocatalytic H2O2 Production
Photocatalytic H2O2 production is an environmentally friendly and sustainable production
technique. Here, we fabricate the Ti3C2 quantum dot-modified defective inverse opal g …
technique. Here, we fabricate the Ti3C2 quantum dot-modified defective inverse opal g …
Electronic Structure and Reactivity of Mononuclear Nonheme Iron–Peroxo Complexes as a Biomimetic Model of Rieske Oxygenases: Ring Size Effects of Macrocyclic …
We report the macrocyclic ring size–electronic structure–electrophilic reactivity correlation of
mononuclear nonheme iron (III)-peroxo complexes bearing N-tetramethylated cyclam …
mononuclear nonheme iron (III)-peroxo complexes bearing N-tetramethylated cyclam …
Seeing the cis-Dihydroxylating Intermediate: A Mononuclear Nonheme Iron-Peroxo Complex in cis-Dihydroxylation Reactions Modeling Rieske Dioxygenases
The nature of reactive intermediates and the mechanism of the cis-dihydroxylation of arenes
and olefins by Rieske dioxygenases and synthetic nonheme iron catalysts have been the …
and olefins by Rieske dioxygenases and synthetic nonheme iron catalysts have been the …
Enhanced Photocatalytic Production of H2O2 through Regulation of Spatial Charge Transfer and Light Absorption over a MnIn2S4/WO3 (Yb, Tm) Z-Scheme …
X Dang, S Wu, H Zhao - ACS Sustainable Chemistry & …, 2022 - ACS Publications
The photocatalytic production of hydrogen peroxide (H2O2) from H2O and O2 is a promising
approach, owing to its advantage of utilization of green solar energy without addition of …
approach, owing to its advantage of utilization of green solar energy without addition of …
Mononuclear Non-Heme Manganese-Catalyzed Enantioselective cis-Dihydroxylation of Alkenes Modeling Rieske Dioxygenases
J Chen, J Zhang, Y Sun, Y Xu, Y Yang… - Journal of the …, 2023 - ACS Publications
The practical catalytic enantioselective cis-dihydroxylation of olefins that utilize earth-
abundant first-row transition metal catalysts under environmentally friendly conditions is an …
abundant first-row transition metal catalysts under environmentally friendly conditions is an …
Biologically inspired nonheme iron complex-catalyzed cis-dihydroxylation of alkenes modeling Rieske dioxygenases
The development of selective catalytic oxidation systems for alkene cis-dihydroxylation
under environmentally benign conditions is an important goal that has long been pursued in …
under environmentally benign conditions is an important goal that has long been pursued in …