Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Enzymes are the core for biological transformations in nature. Their structures and functions
have drawn enormous attention from biologists as well as chemists since last century. The …

Recognizing Nature's unique ability to perform challenging oxygenation reactions with
exquisite selectivity parameters at iron-dependent oxygenases, chemists have long sought …

Chiral hydroxylamines are increasingly common structural elements in pharmaceuticals and
agrochemicals, but their asymmetric synthesis remains challenging. Although …

Photocatalytic H2O2 production is an environmentally friendly and sustainable production
technique. Here, we fabricate the Ti3C2 quantum dot-modified defective inverse opal g …

We report the macrocyclic ring size–electronic structure–electrophilic reactivity correlation of
mononuclear nonheme iron (III)-peroxo complexes bearing N-tetramethylated cyclam …

The nature of reactive intermediates and the mechanism of the cis-dihydroxylation of arenes
and olefins by Rieske dioxygenases and synthetic nonheme iron catalysts have been the …

The photocatalytic production of hydrogen peroxide (H2O2) from H2O and O2 is a promising
approach, owing to its advantage of utilization of green solar energy without addition of …

The practical catalytic enantioselective cis-dihydroxylation of olefins that utilize earth-
abundant first-row transition metal catalysts under environmentally friendly conditions is an …

The development of selective catalytic oxidation systems for alkene cis-dihydroxylation
under environmentally benign conditions is an important goal that has long been pursued in …