Bond-forming and-breaking reactions at sulfur (IV): sulfoxides, sulfonium salts, sulfur ylides, and sulfinate salts

D Kaiser, I Klose, R Oost, J Neuhaus… - Chemical …, 2019 - ACS Publications
Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Synthetic organic electrochemical methods since 2000: on the verge of a renaissance

M Yan, Y Kawamata, PS Baran - Chemical Reviews, 2017 - ACS Publications
Electrochemistry represents one of the most intimate ways of interacting with molecules. This
review discusses advances in synthetic organic electrochemistry since 2000. Enabling …

[HTML][HTML] Electrochemical strategies for C–H functionalization and C–N bond formation

MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …

Modern electrochemical aspects for the synthesis of value‐added organic products

S Möhle, M Zirbes, E Rodrigo, T Gieshoff… - Angewandte Chemie …, 2018 - Wiley Online Library
The use of electricity instead of stoichiometric amounts of oxidizers or reducing agents in
synthesis is very appealing for economic and ecological reasons, and represents a major …

Electrocatalytic C–H Activation

N Sauermann, TH Meyer, Y Qiu, L Ackermann - Acs Catalysis, 2018 - ACS Publications
C–H activation has emerged as a transformative tool in molecular synthesis, but until
recently oxidative C–H activations have largely involved the use of stoichiometric amounts of …

Electrogenerated cationic reactive intermediates: the pool method and further advances

J Yoshida, A Shimizu, R Hayashi - Chemical reviews, 2017 - ACS Publications
Electrochemistry serves as a powerful method for generating reactive intermediates, such as
organic cations. In general, there are two ways to use reactive intermediates for chemical …

New bisoxazoline ligands enable enantioselective electrocatalytic cyanofunctionalization of vinylarenes

N Fu, L Song, J Liu, Y Shen, JC Siu… - Journal of the American …, 2019 - ACS Publications
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective
catalytic methods powered by electricity remain rare. In this work, we report the development …

The applications of dimethyl sulfoxide as reagent in organic synthesis

XF Wu, K Natte - Advanced Synthesis & Catalysis, 2016 - Wiley Online Library
Dimethyl sulfoxide (DMSO) is one of the most commonly applied organic solvents in
chemical transformations and is utilized widely in industrial processes as well. During the …

DMSO-catalysed late-stage chlorination of (hetero) arenes

S Song, X Li, J Wei, W Wang, Y Zhang, L Ai, Y Zhu… - Nature Catalysis, 2020 - nature.com
The chlorination of a bioactive compound can change its physiological properties and
improve its pharmacokinetic and pharmacological profiles. It therefore has been an …

Radical C H Functionalization of Heteroarenes under Electrochemical Control

AG O'Brien, A Maruyama, Y Inokuma… - Angewandte Chemie …, 2014 - Wiley Online Library
Electrochemical reactions are shown to be effective for the C H functionalization of a
number of heterocyclic substrates that are recalcitrant to conventional peroxide radical …