Bond-forming and-breaking reactions at sulfur (IV): sulfoxides, sulfonium salts, sulfur ylides, and sulfinate salts
D Kaiser, I Klose, R Oost, J Neuhaus… - Chemical …, 2019 - ACS Publications
Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …
development of novel chemical structures and architectures. Prominent among these …
Synthetic organic electrochemical methods since 2000: on the verge of a renaissance
Electrochemistry represents one of the most intimate ways of interacting with molecules. This
review discusses advances in synthetic organic electrochemistry since 2000. Enabling …
review discusses advances in synthetic organic electrochemistry since 2000. Enabling …
[HTML][HTML] Electrochemical strategies for C–H functionalization and C–N bond formation
MD Kärkäs - Chemical Society Reviews, 2018 - pubs.rsc.org
Conventional methods for carrying out carbon–hydrogen functionalization and carbon–
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …
nitrogen bond formation are typically conducted at elevated temperatures, and rely on …
Modern electrochemical aspects for the synthesis of value‐added organic products
S Möhle, M Zirbes, E Rodrigo, T Gieshoff… - Angewandte Chemie …, 2018 - Wiley Online Library
The use of electricity instead of stoichiometric amounts of oxidizers or reducing agents in
synthesis is very appealing for economic and ecological reasons, and represents a major …
synthesis is very appealing for economic and ecological reasons, and represents a major …
Electrocatalytic C–H Activation
N Sauermann, TH Meyer, Y Qiu, L Ackermann - Acs Catalysis, 2018 - ACS Publications
C–H activation has emerged as a transformative tool in molecular synthesis, but until
recently oxidative C–H activations have largely involved the use of stoichiometric amounts of …
recently oxidative C–H activations have largely involved the use of stoichiometric amounts of …
Electrogenerated cationic reactive intermediates: the pool method and further advances
J Yoshida, A Shimizu, R Hayashi - Chemical reviews, 2017 - ACS Publications
Electrochemistry serves as a powerful method for generating reactive intermediates, such as
organic cations. In general, there are two ways to use reactive intermediates for chemical …
organic cations. In general, there are two ways to use reactive intermediates for chemical …
New bisoxazoline ligands enable enantioselective electrocatalytic cyanofunctionalization of vinylarenes
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective
catalytic methods powered by electricity remain rare. In this work, we report the development …
catalytic methods powered by electricity remain rare. In this work, we report the development …
The applications of dimethyl sulfoxide as reagent in organic synthesis
XF Wu, K Natte - Advanced Synthesis & Catalysis, 2016 - Wiley Online Library
Dimethyl sulfoxide (DMSO) is one of the most commonly applied organic solvents in
chemical transformations and is utilized widely in industrial processes as well. During the …
chemical transformations and is utilized widely in industrial processes as well. During the …
DMSO-catalysed late-stage chlorination of (hetero) arenes
The chlorination of a bioactive compound can change its physiological properties and
improve its pharmacokinetic and pharmacological profiles. It therefore has been an …
improve its pharmacokinetic and pharmacological profiles. It therefore has been an …
Radical C H Functionalization of Heteroarenes under Electrochemical Control
AG O'Brien, A Maruyama, Y Inokuma… - Angewandte Chemie …, 2014 - Wiley Online Library
Electrochemical reactions are shown to be effective for the C H functionalization of a
number of heterocyclic substrates that are recalcitrant to conventional peroxide radical …
number of heterocyclic substrates that are recalcitrant to conventional peroxide radical …