[HTML][HTML] Mechanistic analysis by NMR spectroscopy: A users guide

Y Ben-Tal, PJ Boaler, HJA Dale, RE Dooley… - Progress in nuclear …, 2022 - Elsevier
A 'principles and practice'tutorial-style review of the application of solution-phase NMR in the
analysis of the mechanisms of homogeneous organic and organometallic reactions and …

Insertion of Molecular Oxygen into a Gold (III)–Hydride Bond

AS Phearman, Y Ardon, KI Goldberg - Journal of the American …, 2024 - ACS Publications
The use of molecular oxygen as an oxidant in chemical synthesis has significant
environmental and economic benefits, and it is widely used as such in large-scale industrial …

[PDF][PDF] Nuclear magnetic resonance spectroscopy

CD Ridge - 2022 - toc.library.ethz.ch
Resonance Spectroscopy Page 1 Nuclear Magnetic Resonance Spectroscopy An Introduction
to Principles, Applications, and Experimental Methods Joseph B. Lambert Trinity University …

Rhodium-catalyzed arene alkenylation using only dioxygen as the oxidant

W Zhu, TB Gunnoe - ACS Catalysis, 2020 - ACS Publications
We report the oxidative conversion of unactivated arenes and alkenes to alkenyl arenes
using unpurified air or purified dioxygen as the only oxidant. This method uses RhCl3 salt as …

Functional group tolerant hydrogen borrowing C-alkylation

EP Bailey, TJ Donohoe, MD Smith - Nature Communications, 2024 - nature.com
Hydrogen borrowing is an attractive and sustainable strategy for carbon–carbon bond
formation that enables alcohols to be used as alkylating reagents in place of alkyl halides …

Sodium pyruvate as a peroxide scavenger in aerobic oxidation under carbene catalysis

G Wang, C Wei, X Hong, Z Fu, W Huang - Green Chemistry, 2020 - pubs.rsc.org
NHC-Catalyzed aerobic oxidative reactions of imines and aldehydes have been developed
by using sodium pyruvate as a novel and efficient peroxide scavenger. A structurally diverse …

TEMPO and a co-reductant mediated aerobic epoxidation of olefins using a new magnetically recoverable iron (iii) bis (phenol) diamine complex: experimental and …

P Mohammadpour, E Safaei, E Mazarei… - Physical Chemistry …, 2023 - pubs.rsc.org
A magnetically recoverable catalyst of an iron (III) bis (phenol) diamine complex immobilized
onto amine functionalized silica-coated magnetic nanoparticles has been synthesized. The …

Visible light driven generation and alkyne insertion reactions of stable bis-cyclometalated Pt (iv) hydrides

D Poveda, Á Vivancos, D Bautista… - Chemical …, 2020 - pubs.rsc.org
Hydride complexes resulting from the oxidative addition of C–H bonds are intermediates in
hydrocarbon activation and functionalization reactions. The discovery of metal systems that …

Mechanisms and Kinetics Studies of Butylated Hydroxytoluene Degradation to Isobutene

J Zhou, H Chen, J Chen, D Wan, H Zhang… - The Journal of …, 2022 - ACS Publications
2, 6-Di-tert-butyl-hydroxytotulene (BHT) is a widely used antioxidant in various fields. In this
study, we explored comprehensively the mechanisms and kinetics of BHT degradation to …

Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water

Y Shimoyama, Y Kitagawa, Y Ohgomori, Y Kon… - Chemical …, 2021 - pubs.rsc.org
A hetero-dinuclear IrIII–CuII complex with two adjacent sites was employed as a catalyst for
the aerobic oxidation of aromatic olefins driven by formate in water. An IrIII–H intermediate …