Publisher Summary The chemistry of metal–alkynyl compounds is developing at a rapid
pace. The bonds of alkynyl ligands, like those of organic alkynes have been shown to …

The concept of a molecular-based electronic technology has been evolving for over 50
years, and the development of molecular designs for such components over this period has …

Silver triflate was found to be an efficient catalyst for the cyclopropenation of internal alkynes
using donor-/acceptor-substituted diazo compounds as carbenoid precursors. Highly …

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Gas-phase HeI and He II photoelectron spectroscopy is used'to experimentally determine
the bonding interactions of V-acetylideligands in (t; 5-C5H5) Fe (CO) 2C= CR compounds …

Selective oxidation of various aromatic alcohols to aldehydes has been carried out with very
high conversion (90%) and selectivity (90%) for aldehydes using cyclopentadienyl …

The detection and removal of heavy metals in the environment is urgent and meaningful. In
this work, two types of fluorescent functionalized silks OSP and ASP have been prepared …

The electronic structure of a series of η1-acetylide complexes containing electron-rich
ruthenium centers is examined using approximate density functional theory. Calculations …

Reaction of [MoCl (η5-C5H5)(CO) 3] with propargyl alcohols HC CCR1R2OH in the
presence of catalytic amounts of CuI and using NEt2H as solvent results in the formation of …