Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Atomic layer deposition on porous materials: Problems with conventional approaches to catalyst and fuel cell electrode preparation

TM Onn, R Küngas, P Fornasiero, K Huang, RJ Gorte - Inorganics, 2018 - mdpi.com
Atomic layer deposition (ALD) offers exciting possibilities for controlling the structure and
composition of surfaces on the atomic scale in heterogeneous catalysts and solid oxide fuel …

Atomic Layer Deposition for Preparing Isolated Co Sites on SiO2 for Ethane Dehydrogenation Catalysis

R Huang, Y Cheng, Y Ji, RJ Gorte - Nanomaterials, 2020 - mdpi.com
Unlike Co clusters, isolated Co atoms have been shown to be selective for catalytic
dehydrogenation of ethane to ethylene; however, preparation of isolated Co sites requires …

Tandem CO2 Valorization and Ethane Dehydrogenation: Elucidating the Nature of Highly Selective Iron Oxide Active Sites

M Tasioula, E de Clermont Gallerande… - ACS …, 2023 - ACS Publications
Iron oxide-based catalysts can selectively covert CO2 to added-value CO in parallel with on-
purpose ethylene production via ethane dehydrogenation (CO2-EDH). The 5Fe/10NiMgZr …

A perspective on thin-film perovskites as supports for metal catalysts

X Mao, C Lin, GW Graham, RJ Gorte - ACS Catalysis, 2020 - ACS Publications
Perovskite-supported metals have sometimes been referred to as “intelligent catalysts”
because of the potential to regenerate sintered particles by driving the metal into the oxide …

A Study of Support Effects for CH4 and CO Oxidation over Pd Catalysts on ALD-Modified Al2O3

X Mao, A Foucher, EA Stach, RJ Gorte - Catalysis Letters, 2019 - Springer
Interactions between a metal and its oxide support can influence CO and CH 4 oxidation, but
promotion by the support can be difficult to study because oxides can have different surface …

Growth of ZrO2 films on mesoporous silica sieve via atomic layer deposition

LF Rasteiro, MA Motin, LH Vieira, EM Assaf, F Zaera - Thin Solid Films, 2023 - Elsevier
The atomic layer deposition of ZrO 2 thin films over the mesopores of a mesoporous silica
sieve, SBA-15 (Santa Barbara Amorphous-15), using the tetrakis (dimethylamino) zirconium …

A Career in Catalysis: Raymond J. Gorte

OA Abdelrahman, EI Altman, M Cargnello… - ACS …, 2024 - ACS Publications
Ray Gorte has made major contributions to catalysis science and engineering in several
fields throughout his more than 40 years career spanning surface science, solid acids, fuel …

“Intelligent” Pt Catalysts Studied on High-Surface-Area CaTiO3 Films

C Lin, AC Foucher, Y Ji, CD Curran, EA Stach… - ACS …, 2019 - ACS Publications
CaTiO3-supported Pt is sometimes referred to as an “Intelligent” catalyst because Pt can
reversibly leave or enter the perovskite lattice following high-temperature reduction or …

Direct Hydrodeoxygenation of m-Cresol to Toluene over Bifunctional NbOx–Pt

T Chen, JM Vohs - The Journal of Physical Chemistry C, 2020 - ACS Publications
This study compared the hydrodeoxygenation (HDO) of m-cresol over Pt and NbO x-
modified Pt catalysts. Reactivity measurements demonstrated that Pt supported on carbon …