[FeFe]-Hydrogenases: maturation and reactivity of enzymatic systems and overview of biomimetic models
JT Kleinhaus, F Wittkamp, S Yadav… - Chemical Society …, 2021 - pubs.rsc.org
While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …
hydrogen since a very long time as an energy carrier and storage molecule. Among the …
Hydrogenase enzymes and their synthetic models: the role of metal hydrides
Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …
Characterizing photocatalysts for water splitting: from atoms to bulk and from slow to ultrafast processes
C Kranz, M Wächtler - Chemical Society Reviews, 2021 - pubs.rsc.org
Research on light-driven catalysis has gained tremendous importance due to the ever-
increasing power consumption and the threatening situation of global warming related to …
increasing power consumption and the threatening situation of global warming related to …
Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts
KJ Lee, N Elgrishi, B Kandemir… - Nature Reviews Chemistry, 2017 - nature.com
Modern energy challenges have amplified interest in transition metal-based molecular
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …
Recent developments in hydrogen evolving molecular cobalt (II)–polypyridyl catalysts
The search for efficient noble metal-free hydrogen-evolving catalysts is the subject of intense
research activity. A new family of molecular cobalt (II)–polypyridyl catalysts has recently …
research activity. A new family of molecular cobalt (II)–polypyridyl catalysts has recently …
Hydrogen evolution with hot electrons on a plasmonic-molecular catalyst hybrid system
A Dey, A Mendalz, A Wach, RB Vadell… - Nature …, 2024 - nature.com
Plasmonic systems convert light into electrical charges and heat, mediating catalytic
transformations. However, there is ongoing controversy regarding the involvement of hot …
transformations. However, there is ongoing controversy regarding the involvement of hot …
Time-Resolved IR Spectroscopy Reveals a Mechanism with TiO2 as a Reversible Electron Acceptor in a TiO2–Re Catalyst System for CO2 Photoreduction
M Abdellah, AM El-Zohry, LJ Antila… - Journal of the …, 2017 - ACS Publications
Attaching the phosphonated molecular catalyst [ReIBr (bpy)(CO) 3] 0 to the wide-bandgap
semiconductor TiO2 strongly enhances the rate of visible-light-driven reduction of CO2 to …
semiconductor TiO2 strongly enhances the rate of visible-light-driven reduction of CO2 to …
Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H2-Evolution Catalysts
N Elgrishi, DA Kurtz, JL Dempsey - Journal of the American …, 2017 - ACS Publications
The need for benchmarking hydrogen evolution catalysts has increasingly been recognized.
The influence of acid choice on activity is often reduced to the overpotential for catalysis …
The influence of acid choice on activity is often reduced to the overpotential for catalysis …
Ultrafast charge transfer dynamics in 2D covalent organic frameworks/Re-complex hybrid photocatalyst
Abstract Rhenium (I)-carbonyl-diimine complexes have emerged as promising
photocatalysts for carbon dioxide reduction with covalent organic frameworks recognized as …
photocatalysts for carbon dioxide reduction with covalent organic frameworks recognized as …
Iron carbonyl compounds with aromatic dithiolate bridges as organometallic mimics of [FeFe] hydrogenases
S Gao, Y Liu, Y Shao, D Jiang, Q Duan - Coordination Chemistry Reviews, 2020 - Elsevier
Recently, substantial efforts had been made in the field of synthetic iron compounds as
structural and functional models of the hydrogenase enzyme active site for the purpose of …
structural and functional models of the hydrogenase enzyme active site for the purpose of …