Covalent organic frameworks

KT Tan, S Ghosh, Z Wang, F Wen… - Nature Reviews …, 2023 - nature.com
The dream to prepare well-defined materials drives the methodological evolution for
molecular synthesis, structural control and materials manufacturing. Among various …

Structural analysis of molecular materials using the pair distribution function

MW Terban, SJL Billinge - Chemical Reviews, 2021 - ACS Publications
This is a review of atomic pair distribution function (PDF) analysis as applied to the study of
molecular materials. The PDF method is a powerful approach to study short-and …

Using sound to synthesize covalent organic frameworks in water

W Zhao, P Yan, H Yang, M Bahri, AM James, H Chen… - Nature …, 2022 - nature.com
Covalent organic frameworks (COFs) are typically synthesized using solvothermal
conditions (> 120° C,> 72 hours) in harmful organic solvents. Here we report a strategy to …

Time‐resolved in situ monitoring of mechanochemical reactions

AAL Michalchuk, F Emmerling - … Chemie International Edition, 2022 - Wiley Online Library
Mechanochemical transformations offer environmentally benign synthesis routes, whilst
enhancing both the speed and selectivity of reactions. In this regard, mechanochemistry …

Transformation of an imine cage to a covalent organic framework film at the liquid–liquid interface

A Giri, G Shreeraj, TK Dutta, A Patra - Angewandte Chemie, 2023 - Wiley Online Library
Dynamic covalent chemistry (DCC) opens up a fascinating route for the construction of well‐
organized supramolecular architectures, starting from organic molecular cages to crystalline …

Covalent organic frameworks in heterogeneous catalysis: Recent advances and future perspective

Z Alsudairy, N Brown, A Campbell, A Ambus… - Materials Chemistry …, 2023 - pubs.rsc.org
Catalysis is ubiquitous in∼ 90% of chemical manufacturing processes and contributes up to
35% of global GDP. Hence, the development of advanced catalytic systems is of utmost …

Green mechanochemical synthesis of imine-linked covalent organic frameworks for high iodine capture

N Brown, Z Alsudairy, R Behera, F Akram, K Chen… - Green …, 2023 - pubs.rsc.org
Covalent organic frameworks (COFs) have emerged as promising adsorbents for
radioiodine capture. However, the conventional solvothermal synthesis contradicts the …

Toward Mechanistic Understanding of Mechanochemical Reactions Using Real-Time In Situ Monitoring

S Lukin, LS Germann, T Friščić… - Accounts of chemical …, 2022 - ACS Publications
Conspectus The past two decades have witnessed a rapid emergence of interest in
mechanochemistry–chemical and materials reactivity achieved or sustained by the action of …

Beyond solvothermal: Alternative synthetic methods for covalent organic frameworks

J Hu, Z Huang, Y Liu - Angewandte Chemie International …, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) are crystalline porous organic materials that hold a
wealth of potential applications across various fields. The development of COFs, however, is …

Polycrystalline covalent organic frameworks

C Qian, WL Teo, Q Gao, H Wu, Y Liao, Y Zhao - Materials Today, 2023 - Elsevier
Covalent organic frameworks (COFs) are a promising class of crystalline porous polymers
formed by reticulating organic units into two-dimensional (2D) or three-dimensional (3D) …