Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …

Remote meta selective C–H functionalization of aromatic compounds remains a challenging
problem in chemical synthesis. Here, we report an iridium catalyst bearing a bidentate …

C− H activation is an attractive methodology to increase molecular complexity without
requiring substrate prefunctionalization. In contrast to well‐established cross‐coupling …

Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …

An efficient method for Ir-catalyzed ligand free ortho borylation of arenes (such as, 2-
phenoxypyridines, 2-anilinopyridines, benzylamines, benzylpiperazines …

Site-selective functionalization of simple arenes remains a paramount challenge due to the
similarity of multiple C–H bonds in the same molecule with similar steric environment and …

Iridium‐catalyzed borylations of aromatic C− H bonds are highly attractive transformations
because of the diversification possibilities offered by the resulting boronates. These …

Non-metal-catalyzed C–H borylation of arenes represents a sustainable and environment-
friendly approach for the functionalization of arenes. Despite its promise as an alternative to …