Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Compound copper chalcogenide nanocrystals

C Coughlan, M Ibanez, O Dobrozhan, A Singh… - Chemical …, 2017 - ACS Publications
This review captures the synthesis, assembly, properties, and applications of copper
chalcogenide NCs, which have achieved significant research interest in the last decade due …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - ACS Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

The surface science of nanocrystals

MA Boles, D Ling, T Hyeon, DV Talapin - Nature materials, 2016 - nature.com
All nanomaterials share a common feature of large surface-to-volume ratio, making their
surfaces the dominant player in many physical and chemical processes. Surface ligands …

Selective Photocatalytic CO2 Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals

MF Kuehnel, KL Orchard, KE Dalle… - Journal of the American …, 2017 - ACS Publications
Photocatalytic conversion of CO2 into carbonaceous feedstock chemicals is a promising
strategy to mitigate greenhouse gas emissions and simultaneously store solar energy in …

[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities

C Coperet, A Comas-Vives, MP Conley… - Chemical …, 2016 - ACS Publications
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …

Charge transport in strongly coupled quantum dot solids

CR Kagan, CB Murray - Nature nanotechnology, 2015 - nature.com
The emergence of high-mobility, colloidal semiconductor quantum dot (QD) solids has
triggered fundamental studies that map the evolution from carrier hopping through localized …

Efficient, Selective CO2 Photoreduction Enabled by Facet-Resolved Redox-Active Sites on Colloidal CdS Nanosheets

N Wang, S Cheong, DE Yoon, P Lu, H Lee… - Journal of the …, 2022 - ACS Publications
Advances in nanotechnology have enabled precise design of catalytic sites for CO2
photoreduction, pushing product selectivity to near unity. However, activity of most …

Prospects of nanoscience with nanocrystals

MV Kovalenko, L Manna, A Cabot, Z Hens… - ACS …, 2015 - ACS Publications
Colloidal nanocrystals (NCs, ie, crystalline nanoparticles) have become an important class
of materials with great potential for applications ranging from medicine to electronic and …

Tunable near-infrared and visible-light transmittance in nanocrystal-in-glass composites

A Llordés, G Garcia, J Gazquez, DJ Milliron - Nature, 2013 - nature.com
Amorphous metal oxides are useful in optical,, electronic,, and electrochemical devices,. The
bonding arrangement within these glasses largely determines their properties, yet it remains …