Detecting interplay of chirality, water, and interfaces for elucidating biological functions
Conspectus Chemists have long been fascinated by chirality, water, and interfaces, making
tremendous progress in each research area. However, the chemistry emerging from the …
tremendous progress in each research area. However, the chemistry emerging from the …
Nonlinear optical probes of nucleation and crystal growth: recent progress and future prospects
AR Dok, T Legat, Y de Coene… - Journal of Materials …, 2021 - pubs.rsc.org
In situ experimental studies have been key in uncovering the often elusive pathways of
nucleation and crystal growth. In the field of material science and medicine this offers the …
nucleation and crystal growth. In the field of material science and medicine this offers the …
Chiral sum frequency generation spectroscopy detects double-helix dna at interfaces
Many DNA-based technologies involve the immobilization of DNA and therefore require a
fundamental understanding of the DNA structure–function relationship at interfaces. We …
fundamental understanding of the DNA structure–function relationship at interfaces. We …
Mirror-image antiparallel β-sheets organize water molecules into superstructures of opposite chirality
Biomolecular hydration is fundamental to biological functions. Using phase-resolved chiral
sum-frequency generation spectroscopy (SFG), we probe molecular architectures and …
sum-frequency generation spectroscopy (SFG), we probe molecular architectures and …
Chiral water superstructures around antiparallel β-sheets observed by chiral vibrational sum frequency generation spectroscopy
Hydration modulates every aspect of protein structure and function. However, studying water
structures in hydration shells remains challenging mostly due to overwhelming background …
structures in hydration shells remains challenging mostly due to overwhelming background …
Iron (III) speciation observed at aqueous and glycerol surfaces: vibrational sum frequency and X-ray
Aqueous solutions of FeCl3 have been widely studied to shed light on a number of
processes from dissolution, mineralization, biology, electrocatalysis, corrosion, to microbial …
processes from dissolution, mineralization, biology, electrocatalysis, corrosion, to microbial …
How Thick is the Air–Water Interface?─ A Direct Experimental Measurement of the Decay Length of the Interfacial Structural Anisotropy
The air–water interface is a highly prevalent phase boundary impacting many natural and
artificial processes. The significance of this interface arises from the unique properties of …
artificial processes. The significance of this interface arises from the unique properties of …
Symmetry-based identification and enumeration of independent tensor properties in nonlinear and chiral optics
DL Andrews - The Journal of Chemical Physics, 2023 - pubs.aip.org
For many laser-based methods of material characterization and analysis, a tensor
formulation of theory is necessary, especially in techniques that exploit nonlinear or chiral …
formulation of theory is necessary, especially in techniques that exploit nonlinear or chiral …
Theoretical basis for interpreting heterodyne chirality-selective sum frequency generation spectra of water
D Konstantinovsky, T Santiago, M Tremblay… - The Journal of …, 2024 - pubs.aip.org
Chirality-selective vibrational sum frequency generation (chiral SFG) spectroscopy has
emerged as a powerful technique for the study of biomolecular hydration water due to its …
emerged as a powerful technique for the study of biomolecular hydration water due to its …
Local ordering of lattice self-assembled SDS@ 2β-CD materials and adsorbed water revealed by vibrational sum frequency generation microscope
VSFG (vibrational sum frequency generation) microscopy was used to study the SDS@ 2β-
CD system, a synthetic capsid-like self-assembled material. We found because of strong …
CD system, a synthetic capsid-like self-assembled material. We found because of strong …