A Dibenzotetrathiafulvalene-Bridged Bis (alkenylruthenium) Complex and Its One-and Two-Electron-Oxidized Forms

FS Gogesch, LS Laininger, N Sokov… - Inorganic …, 2023 - ACS Publications
We report on the synthesis of the new bis (alkenylruthenium) complex DBTTF-(ViRu) 2 with
a longitudinally extended, π-conjugated dibenzotetrathiafulvalene (DBTTF) bridge …

Pyrene fluorescence in 2, 7-di (4-phenylethynyl) pyrene-bridged bis (alkenylruthenium) complexes

FS Gogesch, L Bauer, FD Vollstädt, M Linseis… - Dalton …, 2024 - pubs.rsc.org
Complexes PyrDPE-RuCl and PyrDPE-Ruacac with a π-extended 2, 7-di (4-phenylethynyl)
pyrene linker undergo simultaneous one-electron oxidations of their {Ru}-styryl entities. The …

Organic binary charge-transfer compounds of 2, 2′: 6′, 2′′: 6′′, 6-trioxotriphenylamine and a pyrene-annulated azaacene as donors

R Das, M Linseis, SM Schupp, FS Gogesch… - RSC …, 2023 - pubs.rsc.org
Three binary charge-transfer (CT) compounds resulting from the donor 2, 2′: 6′, 2′′:
6′′, 6-trioxotriphenylamine (TOTA) and the acceptors F4TCNQ and F4BQ and of a pyrene …

Manipulating Intramolecular Charge Transfer and Supramolecular Interaction in D–A–D Conjugated Systems by Regioisomerization

J Fang, D An, W Chen, S Liu, X Lu… - The Journal of Organic …, 2024 - ACS Publications
Three new donor–acceptor–donor (D–A–D) architecture regioisomers comprising a large
planar electron-withdrawing core tribenzo [a, c, i] phenazine and two identical electron …

Redox–Transmetalation Reactions: Easy Access to Homo- and Heterodimetallic d8,d10 Complexes

L Tarifa, AM Geer, L Asensio, JA López… - Inorganic …, 2023 - ACS Publications
The ability of the imine PyCH═ N–CH2Py (Py= 2-pyridyl, bpi) to behave as a heteroditopic
ligand, which is suitable for creating two separate compartments to host metals in different …

Reversible Multielectron Release from Redox-Active Three-Dimensional Molecular Barrels with Ruthenium-Alkenyl Moieties

R Das, M Linseis, S Scheerer, K Zoller, L Senft… - Inorganic …, 2022 - ACS Publications
Three-dimensional molecular barrels Ru 6-4 and Ru 6-5 were synthesized in high yields
from dinuclear ruthenium-vinyl clamps and tritopic triphenylamine-derived carboxylate …

[HTML][HTML] The influence of phosphine ligands on the redox properties of 1, 4-divinylanthrylene-bridged diruthenium complexes and a derived macrocyclic analog

FS Gogesch, J Rendler, M Linseis, L Senft… - Journal of …, 2024 - Elsevier
We report on a series of dinuclear 1, 4-divinylanthrylene-bridged diruthenium complexes 1A-
Ru-PR 3 with different phosphine ligands (P i Pr 3, P i Pr 2 Me, PPh 3, and PMe 3) and with …

Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts

R Das, M Linseis, L Senft, I Ivanović-Burmazović… - Inorganics, 2022 - mdpi.com
We report on the tetraruthenium macrocycles Ru4-5 and-6 with a π-conjugated pyrene-
appended 5, 8-divinylquinoxaline ligand and either isophthalate or thiophenyl-2, 5 …

Electronically Weakly Coupled 4, 4'-Divinylazoarylenes-Bridged Diruthenium Complexes Featuring Two Ru (PiPr3) 2Cl (CO) Entities

OS Abdel-Rahman - 2024 - researchsquare.com
We report here on novel four 4, 4'-divinylazoarylenes-bridged diruthenium complexes
featuring two Ru (P i Pr 3) 2 Cl (CO) entities with a general formula of [{Ru (P i Pr 3) 2 Cl …