Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Advanced materials by atom transfer radical polymerization

K Matyjaszewski - Advanced Materials, 2018 - Wiley Online Library
Atom transfer radical polymerization (ATRP) has been successfully employed for the
preparation of various advanced materials with controlled architecture. New catalysts with …

[HTML][HTML] Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis

G Szczepaniak, J Jeong, K Kapil, S Dadashi-Silab… - Chemical …, 2022 - pubs.rsc.org
Photoinduced atom transfer radical polymerization (photo-ATRP) has risen to the forefront of
modern polymer chemistry as a powerful tool giving access to well-defined materials with …

Red-light-driven atom transfer radical polymerization for high-throughput polymer synthesis in open air

X Hu, G Szczepaniak… - Journal of the …, 2023 - ACS Publications
Photoinduced reversible-deactivation radical polymerization (photo-RDRP) techniques offer
exceptional control over polymerization, providing access to well-defined polymers and …

From precision polymers to complex materials and systems

JF Lutz, JM Lehn, EW Meijer… - Nature Reviews Materials, 2016 - nature.com
Complex chemical systems, such as living biological matter, are highly organized structures
based on discrete molecules in constant dynamic interactions. These natural materials can …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Visible‐Light‐Mediated Controlled Radical Branching Polymerization in Water

K Kapil, G Szczepaniak, MR Martinez… - Angewandte Chemie …, 2023 - Wiley Online Library
Hyperbranched polymethacrylates were synthesized by green‐light‐induced atom transfer
radical polymerization (ATRP) under biologically relevant conditions in the open air. Sodium …

RNA-polymer hybrids via direct and site-selective acylation with the ATRP initiator and photoinduced polymerization

J Jeong, X Hu, H Murata, G Szczepaniak… - Journal of the …, 2023 - ACS Publications
Combining synthetic polymers with RNA paves the way for creating RNA-based materials
with non-canonical functions. We have developed an acylation reagent that allows for direct …

Functional DNA–polymer conjugates

CJ Whitfield, M Zhang, P Winterwerber, Y Wu… - Chemical …, 2021 - ACS Publications
DNA nanotechnology has seen large developments over the last 30 years through the
combination of solid phase synthesis and the discovery of DNA nanostructures. Solid phase …