Secondary building units, nets and bonding in the chemistry of metal–organic frameworks

DJ Tranchemontagne, JL Mendoza-Cortés… - Chemical Society …, 2009 - pubs.rsc.org
This critical review presents a comprehensive study of transition-metal carboxylate clusters
which may serve as secondary building units (SBUs) towards construction and synthesis of …

Large magnetocaloric effect in a Wells-Dawson type {Ni6Gd 6P6} cage

YZ Zheng, M Evangelisti, REP Winpenny - 2011 - digital.csic.es
Magnetic refrigeration is based on the magnetocaloric effect (MCE) which relies on the
entropy change of a material when placed in a magnetic field. 1 Molecular magnets have …

Co–Gd phosphonate complexes as magnetic refrigerants

YZ Zheng, M Evangelisti, REP Winpenny - Chemical Science, 2011 - pubs.rsc.org
Three 3d–4f phosphonate complexes,[CoII8GdIII8 (μ3-OH) 4 (NO3) 4 (O3PtBu) 8 (O2CtBu)
16],[CoII8GdIII4 (O3PtBu) 6 (O2CtBu) 16] and [CoII4GdIII6 (O3PCH2Ph) 6 (O2CtBu) 14 …

Systematic Study of a Family of Butterfly-Like {M2Ln2} Molecular Magnets (M = MgII, MnIII, CoII, NiII, and CuII; Ln = YIII, GdIII, TbIII, DyIII, HoIII, and ErIII)

E Moreno Pineda, NF Chilton, F Tuna… - Inorganic …, 2015 - ACS Publications
A family of 3d–4f [MII2LnIII2 (μ3-OH) 2 (O2C t Bu) 10] 2–“butterflies”(where MII= Mg, Co, Ni,
and Cu; LnIII= Y, Gd, Tb, Dy, Ho, and Er) and [MnIII2LnIII2 (μ3-O) 2 (O2C t Bu) 10] 2 …

MnII–GdIII Phosphonate Cages with a Large Magnetocaloric Effect

YZ Zheng, EM Pineda, M Helliwell… - Chemistry–A European …, 2012 - infona.pl
Cool cages! The use of phosphonates has led to formation of a family of manganese (II)–
lanthanide (III) heterometallic cages with structurally beautiful cores (see figure). Magnetic …

Molecular amino-phosphonate cobalt–lanthanide clusters

EM Pineda, F Tuna, RG Pritchard, AC Regan… - Chemical …, 2013 - pubs.rsc.org
Molecular amino-phosphonate cobalt –lanthanide clusters - Chemical Communications (RSC
Publishing) DOI:10.1039/C3CC40907D Royal Society of Chemistry View PDF VersionPrevious …

Observation of the influence of dipolar and spin frustration effects on the magnetocaloric properties of a trigonal prismatic {Gd 7} molecular nanomagnet

EM Pineda, G Lorusso, KH Zangana, E Palacios… - Chemical …, 2016 - pubs.rsc.org
We report the synthesis and structure of a molecular {Gd7} cage of the formula (iPr2NH2) 6
[Gd7 (μ3-OH) 3 (CO3) 6 (O2CtBu) 12] which has crystallographic C3h symmetry. Low …

Iron Lanthanide Phosphonate Clusters: {Fe6Ln6P6} WellsDawson-like Structures with D3d Symmetry

EM Pineda, F Tuna, YZ Zheng, SJ Teat… - Inorganic …, 2014 - ACS Publications
Reaction of [Fe3 (μ3-O)(O2C t Bu) 6 (HO2C t Bu) 3](O2C t Bu) and [Ln2 (O2C t Bu) 6 (HO2C
t Bu) 6](Ln= lanthanide) with three different phosphonic acids produce a family of highly …

A pseudo-icosahedral cage {Gd 12} based on aminomethylphosphonate

ZM Zhang, KH Zangana, AK Kostopoulos… - Dalton …, 2016 - pubs.rsc.org
A pseudo-icosahedral cage {Gd 12 } based on aminomethylphosphonate - Dalton Transactions
(RSC Publishing) DOI:10.1039/C6DT00876C Royal Society of Chemistry View PDF …

The formation of heterometallic molecular architectures with 3d-metal atoms linked by carboxylate bridges with alkali and alkaline-earth metal ions or with lanthanides

AA Sidorov, MA Kiskin, GG Aleksandrov… - Russian Journal of …, 2016 - Springer
Data on the synthesis of carboxylate complexes combining transition 3 d metals and diverse
heterometals (Li-, Mg-, and Ln-M (3 d)) are reviewed. The factors that are essential to the …