Mechanism of zeolites crystal growth: new findings and open questions

J Grand, H Awala, S Mintova - CrystEngComm, 2016 - pubs.rsc.org
This paper will review the crystal growth mechanism of zeolites and discuss some of the
latest findings in this field. A great effort has been dedicated in recent years to improving the …

Nano-sized ZSM-5 zeolite synthesized via seeding technique for methanol conversions: A review

A Javdani, J Ahmadpour, F Yaripour - Microporous and Mesoporous …, 2019 - Elsevier
This is a review of the existing studies on the seed-assisted method for synthesis of ZSM-5
zeolite which integrated different types of seeds and different routes for synthesis ZSM-5 via …

Investigation of the physicochemical changes preceding zeolite nucleation in a sodium-rich aluminosilicate gel

L Itani, Y Liu, W Zhang, KN Bozhilov… - Journal of the …, 2009 - ACS Publications
All industrially available zeolites are obtained from hydrogel systems. Unfortunately the level
of understanding of the events preceding zeolite crystallization is far from satisfactory. In this …

Multinuclear MAS NMR Monitoring of the Effect of Silicate Speciation on the Mechanism of Zeolite BEA Formation: Toward Engineering of Crystal Size and …

II Ivanova, EP Andriako, IA Kostyukov… - Crystal Growth & …, 2023 - ACS Publications
Time-resolved in situ 13C, 27Al, and 29Si MAS NMR and ex situ XRD, X-ray fluorescence,
and TG studies have been applied for the elucidation of the mechanisms of hydrothermal …

Simple synthesis recipes of porous materials

JA Martens, J Jammaer, S Bajpe, A Aerts… - Microporous and …, 2011 - Elsevier
Researchers in need of an ordered nanoporous material tend to rely on the original
synthesis protocols which often demand hydrothermal synthesis and involve harsh chemical …

Zeolite beta mechanisms of nucleation and growth

ND Hould, A Foster, RF Lobo - Microporous and mesoporous materials, 2011 - Elsevier
Zeolite beta has been prepared in dilute (H2O/SiO2= 80) and concentrated (H2O/SiO2= 20)
conditions. The rates of zeolite beta nucleation and growth in dilute colloidal solutions have …

Direct synthesis of nanosized-ZSM-5/SBA-15 analog composites from preformed ZSM-5 precursors for improved catalytic performance as cracking catalyst

XH Vu, U Bentrup, M Hunger, R Kraehnert… - Journal of Materials …, 2014 - Springer
Abstract Nanosized-ZSM-5/SBA-15 analog composites (ZSC) were successfully synthesized
in a two-step process from zeolite seed solutions containing intact ZSM-5 nanocrystals …

Structure and colloidal stability of nanosized zeolite beta precursors

ND Hould, S Kumar, M Tsapatsis, V Nikolakis… - Langmuir, 2010 - ACS Publications
We report the mechanism of zeolite beta nucleation and growth at 120° C in Al-containing
solutions. Two solutions with molar compositions 1 SiO2/80 H2O/0.25 TEA2O/4 …

Connectivity analysis of the clear sol precursor of silicalite: are nanoparticles aggregated oligomers or silica particles?

DP Petry, M Haouas, SCC Wong, A Aerts… - The Journal of …, 2009 - ACS Publications
The very first stages of the incorporation of tetraethoxysilane (TEOS) into aqueous
tetrapropylammonium hydroxide (TPAOH) by hydrolysis are investigated to clarify the …

Combination of spray drying encapsulation and steaming transformation toward robust hierarchical zeolite microspheres: Synthesis, formation mechanism and acid …

C Shang, Z Wu, WD Wu, XD Chen - Chemical Engineering Science, 2021 - Elsevier
Binder-free zeolite microspheres with hierarchical porosities are prepared by combining
spray-drying encapsulation and steaming transformation. Amorphous aluminosilicate …