Asymmetric heterogeneous catalysis
M Heitbaum, F Glorius, I Escher - … Chemie International Edition, 2006 - Wiley Online Library
Limited natural resources and an increasing demand for enantiomerically pure compounds
render catalysis and especially heterogeneous asymmetric catalysis a key technology. The …
render catalysis and especially heterogeneous asymmetric catalysis a key technology. The …
Chiral selection on inorganic crystalline surfaces
From synthetic drugs to biodegradable plastics to the origin of life, the chiral selection of
molecules presents both daunting challenges and significant opportunities in materials …
molecules presents both daunting challenges and significant opportunities in materials …
Mineral surfaces, geochemical complexities, and the origins of life
RM Hazen, DA Sverjensky - Cold Spring Harbor …, 2010 - cshperspectives.cshlp.org
Crystalline surfaces of common rock-forming minerals are likely to have played several
important roles in life's geochemical origins. Transition metal sulfides and oxides promote a …
important roles in life's geochemical origins. Transition metal sulfides and oxides promote a …
Chiral surface and geometry of metal nanocrystals
Chirality is a basic property of nature and has great importance in photonics, biochemistry,
medicine, and catalysis. This importance has led to the emergence of the chiral inorganic …
medicine, and catalysis. This importance has led to the emergence of the chiral inorganic …
Enantioselective photoinduced cyclodimerization of a prochiral anthracene derivative adsorbed on helical metal nanostructures
The generation of molecular chirality in the absence of any molecular chiral inductor is
challenging and of fundamental interest for developing a better understanding of …
challenging and of fundamental interest for developing a better understanding of …
Chiral acidic amino acids induce chiral hierarchical structure in calcium carbonate
W Jiang, MS Pacella, D Athanasiadou, V Nelea… - Nature …, 2017 - nature.com
Chirality is ubiquitous in biology, including in biomineralization, where it is found in many
hardened structures of invertebrate marine and terrestrial organisms (for example, spiralling …
hardened structures of invertebrate marine and terrestrial organisms (for example, spiralling …
Enantiospecific electrodeposition of a chiral catalyst
JA Switzer, HM Kothari, P Poizot, S Nakanishi… - Nature, 2003 - nature.com
Many biomolecules are chiral—they can exist in one of two enantiomeric forms that only
differ in that their structures are mirror images of each other. Because only one enantiomer …
differ in that their structures are mirror images of each other. Because only one enantiomer …
Chiral metal surfaces for enantioselective processes
N Shukla, AJ Gellman - Nature Materials, 2020 - nature.com
Chiral surfaces are critical components of enantioselective heterogeneous processes such
as those used to prepare enantiomerically pure pharmaceuticals. While the majority of chiral …
as those used to prepare enantiomerically pure pharmaceuticals. While the majority of chiral …
Episodic sediment accumulation on Amazonian flood plains influenced by El Nino/Southern Oscillation
Continental-scale rivers with a sandy bed sequester a significant proportion of their
sediment load in flood plains. The spatial extent and depths of such deposits have been …
sediment load in flood plains. The spatial extent and depths of such deposits have been …
Heterogeneous enantioselective hydrogenation over cinchona alkaloid modified platinum: mechanistic insights into a complex reaction
Modification of a metal surface by a strongly adsorbed chiral organic molecule has proven to
be an interesting strategy for heterogeneous chiral catalysis. Platinum chirally modified by …
be an interesting strategy for heterogeneous chiral catalysis. Platinum chirally modified by …