Asymmetric heterogeneous catalysis

M Heitbaum, F Glorius, I Escher - … Chemie International Edition, 2006 - Wiley Online Library
Limited natural resources and an increasing demand for enantiomerically pure compounds
render catalysis and especially heterogeneous asymmetric catalysis a key technology. The …

Chiral selection on inorganic crystalline surfaces

RM Hazen, DS Sholl - Nature materials, 2003 - nature.com
From synthetic drugs to biodegradable plastics to the origin of life, the chiral selection of
molecules presents both daunting challenges and significant opportunities in materials …

Mineral surfaces, geochemical complexities, and the origins of life

RM Hazen, DA Sverjensky - Cold Spring Harbor …, 2010 - cshperspectives.cshlp.org
Crystalline surfaces of common rock-forming minerals are likely to have played several
important roles in life's geochemical origins. Transition metal sulfides and oxides promote a …

Chiral surface and geometry of metal nanocrystals

SW Im, HY Ahn, RM Kim, NH Cho, H Kim… - Advanced …, 2020 - Wiley Online Library
Chirality is a basic property of nature and has great importance in photonics, biochemistry,
medicine, and catalysis. This importance has led to the emergence of the chiral inorganic …

Enantioselective photoinduced cyclodimerization of a prochiral anthracene derivative adsorbed on helical metal nanostructures

X Wei, J Liu, GJ Xia, J Deng, P Sun, JJ Chruma… - Nature Chemistry, 2020 - nature.com
The generation of molecular chirality in the absence of any molecular chiral inductor is
challenging and of fundamental interest for developing a better understanding of …

Chiral acidic amino acids induce chiral hierarchical structure in calcium carbonate

W Jiang, MS Pacella, D Athanasiadou, V Nelea… - Nature …, 2017 - nature.com
Chirality is ubiquitous in biology, including in biomineralization, where it is found in many
hardened structures of invertebrate marine and terrestrial organisms (for example, spiralling …

Enantiospecific electrodeposition of a chiral catalyst

JA Switzer, HM Kothari, P Poizot, S Nakanishi… - Nature, 2003 - nature.com
Many biomolecules are chiral—they can exist in one of two enantiomeric forms that only
differ in that their structures are mirror images of each other. Because only one enantiomer …

Chiral metal surfaces for enantioselective processes

N Shukla, AJ Gellman - Nature Materials, 2020 - nature.com
Chiral surfaces are critical components of enantioselective heterogeneous processes such
as those used to prepare enantiomerically pure pharmaceuticals. While the majority of chiral …

Episodic sediment accumulation on Amazonian flood plains influenced by El Nino/Southern Oscillation

R Aalto, L Maurice-Bourgoin, T Dunne… - Nature, 2003 - nature.com
Continental-scale rivers with a sandy bed sequester a significant proportion of their
sediment load in flood plains. The spatial extent and depths of such deposits have been …

Heterogeneous enantioselective hydrogenation over cinchona alkaloid modified platinum: mechanistic insights into a complex reaction

T Bürgi, A Baiker - Accounts of chemical research, 2004 - ACS Publications
Modification of a metal surface by a strongly adsorbed chiral organic molecule has proven to
be an interesting strategy for heterogeneous chiral catalysis. Platinum chirally modified by …