Visible-to-NIR-light activated release: from small molecules to nanomaterials
Photoactivatable (alternatively, photoremovable, photoreleasable, or photocleavable)
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …
Thiourea-mediated halogenation of alcohols
The halogenation of alcohols under mild conditions expedited by the presence of
substoichiometric amounts of thiourea additives is presented. The amount of thiourea added …
substoichiometric amounts of thiourea additives is presented. The amount of thiourea added …
Blue or Near-Infrared Light-Triggered Release of Halogens via Blebbistatin Photocage
Z Situ, W Chen, S Yang, X Fan, F Liu… - The Journal of …, 2022 - ACS Publications
Photocages can provide spatial and temporal control to accurately release the various
chemicals and bioactive groups when excited by light. Although the absorption spectra of …
chemicals and bioactive groups when excited by light. Although the absorption spectra of …
Boosting the Release of Leaving Group from Blebbistatin Derivative Photocages via Enhancing Intramolecular Charge Transfer and Stabilizing Cationic Intermediate
Z Situ, M Lu, W Chen, Z Xie, SL Chen… - The Journal of …, 2023 - ACS Publications
Blebbistatin (Bleb) derivatives are a visible light photocage platform. During the
photocleavage process, intramolecular charge transfer (ICT) and cationic intermediates play …
photocleavage process, intramolecular charge transfer (ICT) and cationic intermediates play …
2-Bromoanthraquinone as a highly efficient photocatalyst for the oxidation of sec-aromatic alcohols: experimental and DFT study
S Liao, J Liu, L Yan, Q Liu, G Chen, L Ma - RSC advances, 2020 - pubs.rsc.org
Anthraquinones are recognized as high efficiency photocatalysts which can perform various
redox reactions in aqueous or organic phases. We have experimentally proven that 2-BrAQ …
redox reactions in aqueous or organic phases. We have experimentally proven that 2-BrAQ …
O‐nitrobenzyl Caged Molecule Enables Photo‐controlled Release of Thiabendazole
W Fu, Z Shao, Z Xu, Z Li, X Shao - ChemBioChem, 2024 - Wiley Online Library
Pesticides are essential in agricultural development. Controlled‐release pesticides have
attracted great attentions. Base on a principle of spatiotemporal selectivity, we extended the …
attracted great attentions. Base on a principle of spatiotemporal selectivity, we extended the …
To photodeprotect or not: effect of the oxidation state of the sulfur atom of thiochromone derivatives
X Li, Y Guo, T Xu, J Wang, M Dai, K Kakiuchi… - Chemical …, 2022 - pubs.rsc.org
Time-resolved spectroscopic experiments, assisted with DFT calculations, were employed to
study the photochemical reaction mechanism of (4-oxo-3-phenyl-4H-thiochromen-2-yl) …
study the photochemical reaction mechanism of (4-oxo-3-phenyl-4H-thiochromen-2-yl) …
Photodeprotection Reaction Mechanisms of Caged Species Utilizing a Photochromism Function
Y Guo, M Dai, DL Phillips, W Xu… - The Journal of Physical …, 2022 - ACS Publications
Acetoxy-1, 2, 2-tri (aryl) ethanone (1) is a novel and visual release-and-report system that
contains the photochromic diarylethylene function attached to the photocage …
contains the photochromic diarylethylene function attached to the photocage …
Review of laser flash photolysis of organic molecules (2015–2018)
This chapter serves as a review of the literature concerning the use of laser flash photolysis
(LFP) in research reported between the years 2015 and 2018. The first half of the chapter …
(LFP) in research reported between the years 2015 and 2018. The first half of the chapter …
The solvent effect on the photodeprotection of anthraquinone protected carboxylic acid unravelled by time-resolved spectroscopic studies
Y Guo, Q Song, T Xu, J Ma, DL Phillips - Physical Chemistry Chemical …, 2019 - pubs.rsc.org
Time-resolved spectroscopy studies coupled with the results from density functional theory
(DFT) computations were utilized to unravel the photodeprotection reaction mechanism (s) …
(DFT) computations were utilized to unravel the photodeprotection reaction mechanism (s) …