Nickel catalyzed olefin oligomerization and dimerization

H Olivier-Bourbigou, PAR Breuil, L Magna… - Chemical …, 2020 - ACS Publications
Brought to life more than half a century ago and successfully applied for high-value
petrochemical intermediates production, nickel-catalyzed olefin oligomerization is still a very …

Recent advances in Ni-mediated ethylene chain growth: Nimine-donor ligand effects on catalytic activity, thermal stability and oligo-/polymer structure

Z Wang, Q Liu, GA Solan, WH Sun - Coordination Chemistry Reviews, 2017 - Elsevier
Homogeneous nickel catalysts have a considerable track record for mediating ethylene
chain growth in the form of oligomerization and more recently polymerization. Within the …

Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands

C Fliedel, A Ghisolfi, P Braunstein - Chemical reviews, 2016 - ACS Publications
The aim of this review is to highlight how the diversity generated by N-substitution in the well-
known short-bite ligand bis (diphenylphosphino) amine (DPPA) allows a fine-tuning of the …

Ni-based complexes in selective ethylene oligomerization processes

GE Bekmukhamedov, AV Sukhov, AM Kuchkaev… - Catalysts, 2020 - mdpi.com
Linear alpha-olefins are widely used in the petrochemical industry and the world demand for
these compounds increases annually. At present, the main method for producing linear …

Ethylene oligomerization studies by nickel (II) complexes chelated by (amino) pyridine ligands: Experimental and density functional theory studies

GS Nyamato, SO Ojwach, MP Akerman - Dalton Transactions, 2016 - pubs.rsc.org
Reductions of imine compounds 2-methoxy-N-(1-(pyridin-2-yl) ethylidene) ethanamine (L1),
2-methoxy-N-((pyridin-2-yl) methylene) ethanamine (L2), N, N-diethyl-N-((pyridin-2-yl) …

Monodentate Phosphinoamine Nickel Complex Supported on a Metal–Organic Framework for High‐Performance Ethylene Dimerization

W Chen, P Elumalai, H Mamlouk… - Advanced …, 2024 - Wiley Online Library
Ethylene dimerization is an efficient industrial chemical process to produce 1‐butene, with
demanding selectivity and activity requirements on new catalytic systems. Herein, a series of …

Paradox of late transition-metal catalysts in ethylene polymerization

B Gansukh, R Zhang, J Guo, W Zhang… - General …, 2020 - genchemistry.org
Polyolefin materials are the most synthesized polymer used nowadays and symbolize the
development level of the national petrochemical industry, in which polyethylenes are major …

Ni (II) complexes bearing pyrrolide-imine ligands with pendant N-, O-and S-donor groups: synthesis, structural characterization and use in ethylene oligomerization

AC Pinheiro, AH Virgili, T Roisnel, E Kirillov… - RSC …, 2015 - pubs.rsc.org
A series of new Ni (II) complexes of general formula {L} NiCl [Ni1, L= 2-(C4H3N-2′-CHN)
C2H4NHPh; Ni2, L= 5-tert-butyl-2-(C4H2N-2′-CHN) C2H4NHPh; Ni3, L= 2-(C4H3N-2 …

Tandem ethylene dimerization and Friedel-Crafts alkylation of toluene catalyzed by homo-and heterogeneous nickel (II) and palladium (II) pre-catalysts

K Kumar, T Godeto, J Darkwa - Journal of Organometallic Chemistry, 2016 - Elsevier
Palladium (II) and nickel (II) complexes (1–4) of the Schiff base ligands, N-(2-
pyridinylmethylene)-3-(triethoxysilyl)-1-propanamine (L1) and N-(1-(pyridin-2-yl) ethylidene) …

Thioether-terminated nickel (II) coordination clusters with {Ni 6} horseshoe-and {Ni 8} rollercoaster-shaped cores

S Schmitz, J van Leusen, A Ellern, P Kögerler… - Inorganic Chemistry …, 2016 - pubs.rsc.org
We report two polynuclear nickel (II) compounds whose supramolecular structures are
controlled by small inorganic templating anions and π-conjugated Schiff-base ligands (L …