Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics

A Mandal, MAD Taylor, BM Weight… - Chemical …, 2023 - ACS Publications
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …

Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Theoretical challenges in polaritonic chemistry

J Fregoni, FJ Garcia-Vidal, J Feist - ACS photonics, 2022 - ACS Publications
Polaritonic chemistry exploits strong light–matter coupling between molecules and confined
electromagnetic field modes to enable new chemical reactivities. In systems displaying this …

Unveiling hidden physics at the LHC

O Fischer, B Mellado, S Antusch, E Bagnaschi… - The European Physical …, 2022 - Springer
The field of particle physics is at the crossroads. The discovery of a Higgs-like boson
completed the Standard Model (SM), but the lacking observation of convincing resonances …

Cavity controlled upconversion in cdse nanoplatelet polaritons

M Amin, ER Koessler, O Morshed, F Awan… - ACS …, 2024 - ACS Publications
Exciton-polaritons provide a versatile platform for investigating quantum electrodynamics
effects in chemical systems, such as polariton-altered chemical reactivity. However, using …

Strong coupling between localized surface plasmons and molecules by coupled cluster theory

J Fregoni, TS Haugland, S Pipolo, T Giovannini… - Nano Letters, 2021 - ACS Publications
Plasmonic nanocavities enable the confinement of molecules and electromagnetic fields
within nanometric volumes. As a consequence, the molecules experience a remarkably …

Vacuum-induced symmetry breaking of chiral enantiomer formation in chemical reactions

Y Ke, Z Song, QD Jiang - Physical Review Letters, 2023 - APS
A material with symmetry breaking inside can transmit the symmetry breaking to its vicinity
by vacuum electromagnetic fluctuations. Here, we show that vacuum quantum fluctuations …

Disorder enhanced vibrational entanglement and dynamics in polaritonic chemistry

D Wellnitz, G Pupillo, J Schachenmayer - Communications Physics, 2022 - nature.com
Collectively coupling molecular ensembles to a cavity has been demonstrated to modify
chemical reactions akin to catalysis. Theoretically understanding this experimental finding …

Theory and modeling of light-matter interactions in chemistry: current and future

BM Weight, X Li, Y Zhang - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Light–matter interaction not only plays an instrumental role in characterizing materials'
properties via various spectroscopic techniques but also provides a general strategy to …