Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

[HTML][HTML] Porous metal–organic frameworks for hydrogen storage

D Zhao, X Wang, L Yue, Y He, B Chen - Chemical Communications, 2022 - pubs.rsc.org
The high gravimetric energy density and environmental benefits place hydrogen as a
promising alternative to the widely used fossil fuels, which is however impeded by the lack of …

Metal–organic frameworks: functional luminescent and photonic materials for sensing applications

WP Lustig, S Mukherjee, ND Rudd, AV Desai… - Chemical Society …, 2017 - pubs.rsc.org
Metal–organic frameworks (MOFs) or porous coordination polymers (PCPs) are open,
crystalline supramolecular coordination architectures with porous facets. These chemically …

Solvent-derived defects suppress adsorption in MOF-74

Y Fu, Y Yao, AC Forse, J Li, K Mochizuki… - Nature …, 2023 - nature.com
Defects in metal-organic frameworks (MOFs) have great impact on their nano-scale structure
and physiochemical properties. However, isolated defects are easily concealed when the …

A search for selectivity to enable CO 2 capture with porous adsorbents

M Oschatz, M Antonietti - Energy & Environmental Science, 2018 - pubs.rsc.org
Fundamental aspects and actual developments of selective CO2 capture from relevant
sources (flue gas or air) by reversible physisorption are critically reviewed. Thermodynamic …

Quantum Informed Machine-Learning Potentials for Molecular Dynamics Simulations of CO2's Chemisorption and Diffusion in Mg-MOF-74

B Zheng, FL Oliveira, R Neumann Barros Ferreira… - ACS …, 2023 - ACS Publications
Among various porous solids for gas separation and purification, metal-organic frameworks
(MOFs) are promising materials that potentially combine high CO2 uptake and CO2/N2 …

Brønsted acidity in metal–organic frameworks

J Jiang, OM Yaghi - Chemical reviews, 2015 - ACS Publications
The past 20 years have witnessed rapid development of reticular chemistry, 1, 2 which is
concerned with linking molecular building units with strong chemical bonds to form …

Perspective of microporous metal–organic frameworks for CO 2 capture and separation

Z Zhang, ZZ Yao, S Xiang, B Chen - Energy & environmental science, 2014 - pubs.rsc.org
It is emergent to reduce carbon dioxide emissions from fossil fuel combustion and thereby
limit climate destabilization. In order to achieve the industrial scenario of CCS, there is a …

Applications of metal-organic frameworks featuring multi-functional sites

B Li, M Chrzanowski, Y Zhang, S Ma - Coordination Chemistry Reviews, 2016 - Elsevier
Abstract Metal-organic frameworks (MOFs), a class of porous materials bring great promise
for a diverse array of applications ranging from gas storage and separation to …

Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms

L Li, HS Jung, JW Lee, YT Kang - Renewable and Sustainable Energy …, 2022 - Elsevier
Concern about global warming has led to substantial global-scale efforts to remove CO 2
from both emission sources and the atmosphere. Metal–organic frameworks, which may be …