Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications

J Yan, MR Bockstaller, K Matyjaszewski - Progress in Polymer Science, 2020 - Elsevier
Recent progress in surface-initiated polymerization enables the deliberate polymer
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …

Nitroxides: applications in synthesis and in polymer chemistry

L Tebben, A Studer - Angewandte Chemie International Edition, 2011 - Wiley Online Library
This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …

Nitroxide-mediated radical polymerization: limitations and versatility

RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

The strength of multi-scale modeling to unveil the complexity of radical polymerization

DR D'hooge, PHM Van Steenberge… - Progress in Polymer …, 2016 - Elsevier
The strength of multi-scale modeling to support the fundamental understanding and design
of radical polymerization processes is illustrated, considering both controlled and free …

Controlled radical polymerization: industrial stakes, obstacles and achievements

M Destarac - Macromolecular Reaction Engineering, 2010 - Wiley Online Library
The extraordinary scientific development of controlled radical polymerization (CRP)
contrasts with the very limited number of commercially available products derived from these …

Kinetic subtleties of nitroxide mediated polymerization

D Bertin, D Gigmes, SRA Marque… - Chemical Society Reviews, 2011 - pubs.rsc.org
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …

Recent advances in the design of bioconjugates from controlled/living radical polymerization

B Le Droumaguet, J Nicolas - Polymer Chemistry, 2010 - pubs.rsc.org
Since its discovery, controlled/living radical polymerization (CLRP) has proven to be a
mature technology for building tailor-made (block) copolymers, functional polymers and …

Toward nitroxide-mediated photopolymerization

Y Guillaneuf, D Bertin, D Gigmes, DL Versace… - …, 2010 - ACS Publications
A new alkoxyamine (methyl 2-((4-benzoylphenyl)((1-methoxy-2-methyl-1-oxopropan-2-yl)
oxy) amino)-2-methylpropanoate 4) bearing a chromophore group directly linked to the …