Metal–ligand cooperation (MLC) has become an important concept in catalysis by transition
metal complexes both in synthetic and biological systems. MLC implies that both the metal …

The site-selective formation of carbonrcarbon bonds through direct functionalizations of
otherwise unreactive carbonrhydrogen bonds constitutes an economically attractive strategy …

Carbon–carbon bond cleavage reactions, adapted to deconstruct aliphatic hydrocarbon
polymers and recover the intrinsic energy and carbon value in plastic waste, have typically …

Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

The selective transformation of ubiquitous but inert C–H bonds to other functional groups
has far-reaching practical implications, ranging from more efficient strategies for fine …

Hydrocarbons, especially saturated hydrocarbons (alkanes), are the main constituents of oil
and natural gas, the feedstocks for chemical industry. Therefore, it is obvious that …

Synthetic methods chemistry has undergoneintense development during the past 50 years.
As a result, nearly every class of organic compound can now be considered as a source of …

Surface organometallic chemistry is an area of heterogeneous catalysis which has recently
emerged as a result of a comparative analysis of homogeneous and heterogeneous …

Mechanistic assessments based on kinetic and isotopic methods combined with density
functional theory are used to probe the diverse pathways by which C–H bonds in CH4 react …

Aspects of Methane Chemistry Page 1 Chem. Rev. 1995, 95, 987-1007 987 Aspects of
Methane Chemistry Robert H. Crabtree Department of Chemistry, 225 Prospect Street, Yale …