Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Single-atom alloy catalysis

RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …

Hydrogen spillover in complex oxide multifunctional sites improves acidic hydrogen evolution electrocatalysis

J Dai, Y Zhu, Y Chen, X Wen, M Long, X Wu… - Nature …, 2022 - nature.com
Improving the catalytic efficiency of platinum for the hydrogen evolution reaction is valuable
for water splitting technologies. Hydrogen spillover has emerged as a new strategy in …

Hydrogen spillover as a promising strategy for boosting heterogeneous catalysis and hydrogen storage

M Li, W Yin, J Pan, Y Zhu, N Sun, X Zhang… - Chemical Engineering …, 2023 - Elsevier
Hydrogen spillover, a common active species migration phenomenon, has drawn
tremendous attention in the past few years. The spilled atomic hydrogen can not only …

N‐Coordinated Cu–Ni Dual‐Single‐Atom Catalyst for Highly Selective Electrocatalytic Reduction of Nitrate to Ammonia

Y Wang, H Yin, F Dong, X Zhao, Y Qu, L Wang, Y Peng… - Small, 2023 - Wiley Online Library
As a traditional method of ammonia (NH3) synthesis, Haber–Bosch method expends a vast
amount of energy. An alternative route for NH3 synthesis is proposed from nitrate (NO3−) via …

[HTML][HTML] Magic of hydrogen spillover: Understanding and application

H Shen, H Li, Z Yang, C Li - Green Energy & Environment, 2022 - Elsevier
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …

Facet engineering accelerates spillover hydrogenation on highly diluted metal nanocatalysts

L Jiang, K Liu, SF Hung, L Zhou, R Qin, Q Zhang… - Nature …, 2020 - nature.com
Hydrogen spillover is a well-known phenomenon in heterogeneous catalysis; it involves H2
cleavage on an active metal followed by the migration of dissociated H species over an …

Hydrogen Spillover and Its Relation to Hydrogenation: Observations on Structurally Defined Single‐Atom Sites

MJ Hülsey, V Fung, X Hou, J Wu… - Angewandte Chemie …, 2022 - Wiley Online Library
Hydrogen spillover, involving the transfer of H atoms from metal sites onto the catalyst
support, is ubiquitous in chemical processes such as catalytic hydrogenation and hydrogen …

Dilute alloys based on Au, Ag, or Cu for efficient catalysis: from synthesis to active sites

JD Lee, JB Miller, AV Shneidman, L Sun… - Chemical …, 2022 - ACS Publications
The development of new catalyst materials for energy-efficient chemical synthesis is critical
as over 80% of industrial processes rely on catalysts, with many of the most energy-intensive …

Metal@ zeolite hybrid materials for catalysis

H Wang, L Wang, FS Xiao - ACS Central Science, 2020 - ACS Publications
The fixation of metal nanoparticles into zeolite crystals has emerged as a new series of
heterogeneous catalysts, giving performances that steadily outperform the generally …