Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …

Phosphorus-containing molecules are ubiquitous in the world around us, and the synthetic
and industrial utilization of phosphorus has prospered for over a century. 1, 2 The industrial …

Nitrogenases uniquely reduce atmospheric N2 to bioavailable ammonium. They group into
three isoforms that primarily differ in the architecture of their active-site cofactors. A …

Metal alkynyl complexes hold a fascination for synthetic chemists, structural chemists, and
materials scientists alike. Harnessing the unique overlap of metal and carbon orbitals is a …

Molybdenum complexes that contain the triamidoamine ligand [(RNCH2CH2) 3N] 3−(R= 3,
5‐(2, 4, 6‐iPr3C6H2) 2C6H3) catalyze the reduction of dinitrogen to ammonia at 22° C and …

The identity and oxidation state of the metal in a coordination compound are typically
thought to be the most important determinants of its reactivity. However, the coordination …

A library of low-coordinate titanium and vanadium complexes containing terminal metal−
ligand multiply bonded functionalities such as alkylidenes, alkylidynes, and imides have …

Sterically hindered molybdenum (iii) amido complexes of the general type [Mo {(tBu)(Ar) N}
3](1), upon treatment with CH2Cl2 or other halogen donors, have been converted into highly …

The slow magnetic relaxation typical for single-ion magnets has been known for certain low-
coordinate 3d metal complexes with d6, d7, and d9 electronic configurations, but never for …

Three-coordinate organometallic complexes are rare, especially with the prototypical methyl
ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron …