Anti-Markovnikov intermolecular hydroamination of alkenes and alkynes: a mechanistic view

J Escorihuela, A Lledós, G Ujaque - Chemical Reviews, 2023 - ACS Publications
Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

Late transition metal-catalyzed hydroamination and hydroamidation

L Huang, M Arndt, K Gooßen, H Heydt… - Chemical …, 2015 - ACS Publications
This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Photocatalytic generation of aminium radical cations for C–N bond formation

JM Ganley, PRD Murray, RR Knowles - ACS catalysis, 2020 - ACS Publications
Aminium radical cations have been extensively studied as electrophilic aminating species
that readily participate in C–N bond forming processes with alkenes and arenes. However …

Catalytic enantioselective functionalization of unactivated terminal alkenes

JR Coombs, JP Morken - Angewandte Chemie International …, 2016 - Wiley Online Library
Terminal alkenes are readily available functional groups which appear in α‐olefins
produced by the chemical industry, and they appear in the products of many contemporary …

Anti-Markovnikov hydroamination of unactivated alkenes with primary alkyl amines

DC Miller, JM Ganley, AJ Musacchio… - Journal of the …, 2019 - ACS Publications
We report here a photocatalytic method for the intermolecular anti-Markovnikov
hydroamination of unactivated olefins with primary alkyl amines to selectively furnish …

Hydroamination and hydroaminoalkylation of alkenes by group 3–5 elements: recent developments and comparison with late transition metals

J Hannedouche, E Schulz - Organometallics, 2018 - ACS Publications
This short review highlights recent catalyst developments from group 3–5 elements reported
in the past few years to promote two highly atom-saving transformations, namely …

Recent advances in organo-lanthanides and actinides mediated hydroaminations

H Liu, S Saha, MS Eisen - Coordination Chemistry Reviews, 2023 - Elsevier
Hydroamination, an atom-economic one-step reaction that refers to the addition of an NH
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …

Use of organolanthanides in the catalytic intermolecular hydrophosphination and hydroamination of multiple C–C bonds

AA Trifonov, IV Basalov, AA Kissel - Dalton Transactions, 2016 - pubs.rsc.org
Use of organolanthanides in the catalytic intermolecular hydrophosphination and
hydroamination of multiple C–C bonds - Dalton Transactions (RSC Publishing) DOI:10.1039/C6DT03913H …

Heteroleptic alkyl and amide iminoanilide alkaline earth and divalent rare earth complexes for the catalysis of hydrophosphination and (cyclo) hydroamination …

B Liu, T Roisnel, JF Carpentier… - Chemistry–A European …, 2013 - Wiley Online Library
Abstract [{N^ N} M (X)(thf) n] alkyl (X= CH (SiMe3) 2) and amide (X= N (SiMe3) 2) complexes
of alkaline earths (M= Ca, Sr, Ba) and divalent rare earths (YbII and EuII) bearing an …

Recent metal-catalysed asymmetric hydroaminations of alkenes

C Michon, MA Abadie, F Medina… - Journal of …, 2017 - Elsevier
The selective and asymmetric addition of amines across alkene C= C bonds
(hydroamination of alkenes) is one of the most important tool to synthesise chiral amines …