Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …

Polymers on nanoparticles: structure & dynamics

MJA Hore - Soft Matter, 2019 - pubs.rsc.org
Grafting polymers to nanoparticle surfaces influences properties from the conformation of the
polymer chains to the dispersion and assembly of nanoparticles within a polymeric material …

How tuning interfaces impacts the dynamics and structure of polymer nanocomposites simultaneously

AC Genix, V Bocharova, B Carroll… - … Applied Materials & …, 2023 - ACS Publications
Fundamental understanding of the macroscopic properties of polymer nanocomposites
(PNCs) remains difficult due to the complex interplay of microscopic dynamics and structure …

Mechanism of mechanical reinforcement for weakly attractive nanocomposites in glassy and rubbery states

W Cui, W You, W Yu - Macromolecules, 2021 - ACS Publications
Polymer nanocomposites (PNCs) have been widely investigated due to their significant
performance in mechanical reinforcement, but the mechanism of mechanical reinforcement …

Polymer dynamics under confinement

D Richter, M Kruteva - Soft Matter, 2019 - pubs.rsc.org
We review recent neutron scattering work and related results from simulation and
complementary techniques focusing on the microscopic dynamics of polymers under …

A coupled MD-FE methodology to characterize mechanical interphases in polymeric nanocomposites

M Ries, G Possart, P Steinmann, S Pfaller - International Journal of …, 2021 - Elsevier
This contribution introduces an unconventional procedure to characterize spatial profiles of
elastic and inelastic properties inside polymer interphases around nanoparticles …

Enhancing the mechanical properties of glassy nanocomposites by tuning polymer molecular weight

AC Genix, V Bocharova, A Kisliuk… - … applied materials & …, 2018 - ACS Publications
The addition of nanoparticles to a polymer matrix is a well-known process to improve the
mechanical properties of polymers. Many studies of mechanical reinforcement in polymer …

[HTML][HTML] A quantitative interphase model for polymer nanocomposites: Verification, validation, and consequences regarding size effects

M Ries, F Weber, G Possart, P Steinmann… - Composites Part A …, 2022 - Elsevier
The enhanced mechanical behavior of polymer nanocomposites with spherical filler
particles is attributed to the formation of matrix-filler interphases. The nano-scale leads to …

Interplay of grafted and adsorbed chains at the polymer–particle interface in tuning the mechanical reinforcement in polymer nanocomposites

W Cui, W You, W Yu - ACS Applied Polymer Materials, 2024 - ACS Publications
The polymer–particle interface consisting of grafted and adsorbed chains plays a key role in
the mechanical reinforcement of polymer nanocomposites, but the synergistic effect of …

[HTML][HTML] Effect of surface properties and polymer chain length on polymer adsorption in solution

EY Lin, AL Frischknecht, KI Winey… - The Journal of Chemical …, 2021 - pubs.aip.org
In polymer nanoparticle composites (PNCs) with attractive interactions between
nanoparticles (NPs) and polymers, a bound layer of the polymer forms on the NP surface …