Homogeneity of Supported Single‐Atom Active Sites Boosting the Selective Catalytic Transformations
Selective conversion of specific functional groups to desired products is highly important but
still challenging in industrial catalytic processes. The adsorption state of surface species is …
still challenging in industrial catalytic processes. The adsorption state of surface species is …
The phenomenon of “dead” metal in heterogeneous catalysis: opportunities for increasing the efficiency of carbon-supported metal catalysts
This review addresses the largely overlooked yet critical issue of “dead” metal in
heterogeneous metal catalysts.“Dead” metal refers to the fraction of metal in a catalyst that …
heterogeneous metal catalysts.“Dead” metal refers to the fraction of metal in a catalyst that …
Time-resolved formation and operation maps of pd catalysts suggest a key role of single atom centers in cross-coupling
AS Galushko, DA Boiko, EO Pentsak… - Journal of the …, 2023 - ACS Publications
An approach to the spatially localized characterization of supported catalysts over a reaction
course is proposed. It consists of a combination of scanning, transmission, and high …
course is proposed. It consists of a combination of scanning, transmission, and high …
Well-defined high entropy-metal nanoparticles: Detection of the multi-element particles by deep learning
Characterizing and control the chemical compositions of multi-element particles as single
metal nanoparticles (mNPs) on the surfaces of catalytic metal oxide supports is challenging …
metal nanoparticles (mNPs) on the surfaces of catalytic metal oxide supports is challenging …
4D Catalysis Concept Enabled by Multilevel Data Collection and Machine Learning Analysis
AS Galushko, VP Ananikov - ACS Catalysis, 2023 - ACS Publications
The influence of catalysis on the development of modern science and industry cannot be
overestimated. Production of pharmaceutical substances and drugs, 1, 2 the oil industry, 3 …
overestimated. Production of pharmaceutical substances and drugs, 1, 2 the oil industry, 3 …
Aerobic bacteria-supported biohybrid palladium catalysts for efficient cross-coupling reactions
PV Rybochkin, RN Perchikov, BY Karlinskii… - Journal of …, 2024 - Elsevier
Palladium-based catalysts are of key importance in organic synthesis due to their versatility
and tolerance for a wide range of functional groups. However, their use challenged by …
and tolerance for a wide range of functional groups. However, their use challenged by …
Examination of Pt 2 dba 3 as a “cocktail”-type catalytic system for alkene and alkyne hydrosilylation reactions
EE Ondar, AY Kostyukovich, JV Burykina… - Catalysis Science & …, 2023 - pubs.rsc.org
Recent developments have underpinned that the creation of a potent catalytic system does
not always necessitate the assembly of complex and costly organic ligands with transition …
not always necessitate the assembly of complex and costly organic ligands with transition …
The Fast Formation of a Highly Active Homogeneous Catalytic System upon the Soft Leaching of Pd Species from a Heterogeneous Pd/C Precursor
AS Galushko, VV Ilyushenkova, JV Burykina… - Inorganics, 2023 - mdpi.com
Understanding the interface between soluble metal complexes and supported metal
particles is important in order to reveal reaction mechanisms in a new generation of highly …
particles is important in order to reveal reaction mechanisms in a new generation of highly …
Revealing the mechanism of combining best properties of homogeneous and heterogeneous catalysis in hybrid Pd/NHC systems
DO Prima, NS Kulikovskaya, RA Novikov… - Angewandte Chemie …, 2024 - Wiley Online Library
The formation of transient hybrid nanoscale metal species from homogeneous molecular
precatalysts has been demonstrated by in situ NMR studies of catalytic reactions involving …
precatalysts has been demonstrated by in situ NMR studies of catalytic reactions involving …
Deep learning-assisted analysis of single molecule dynamics from liquid-phase electron microscopy
We apply U-Net and UNet++ to analyze single-molecule movies obtained from liquid-phase
electron microscopy. Neural networks allow full automation, and high throughput analysis of …
electron microscopy. Neural networks allow full automation, and high throughput analysis of …