This Review aims to be a comprehensive, authoritative, and critical review of general
interest to the chemistry community (both academia and industry) as it contains an extensive …

Synthesis of semifluorinated polymers containing fluorous groups on the backbone or as
side chains is an increasingly popular field of research. Introduction of fluorine in polymers …

A new method for the on‐site preparation of tetrafluoroethylene (TFE) and a procedure for its
efficient use in pentafluoroethylation by fluoride addition were developed by using a simple …

Reducing the crystal size of perovskites to the strong quantum confinement regime is an
effective way to realize blue luminescence for light-emitting applications. However …

A new fluorinated azidoethane─ 1-azido-1, 1, 2, 2-tetrafluoroethane─ was prepared in
quantitative yield by the addition of an azide anion to tetrafluoroethylene in a protic medium …

The transition to more economically friendly small-chain fluorinated groups is leading to a
resurgence in the synthesis and reactivity of fluoroalkenes. One versatile method to obtain a …

We herein report the formation of fluorinated N-heterocyclic carbenes (NHCFs) that bear
fluorine atoms at the 4-and 5-positions of the imidazol-2-ylidene ring. Treatment of sodium …

Diverse methods have been reported for the synthesis of acyl fluorides; however, an
environmentally benign synthesis method for acyl fluorides remains underdeveloped. In this …

The Cu (I)‐catalyzed pentafluoroethylation of iodoarenes via the fluorocupration of
tetrafluoroethylene (TFE) is disclosed. The active species,(phen) CuC2F5, was isolated and …

Tetrafluoroethylene (TFE) is an industrial organofluorine feedstock that is used
predominantly to fabricate fluorinated polymers. TFE exhibits excellent potential as a …