Recent Advances in Mono‐and Difunctionalization of Unactivated Olefins

M Patel, B Desai, A Sheth… - Asian Journal of …, 2021 - Wiley Online Library
Olefins are synthetically useful building blocks in modern organic synthesis. Direct
functionalization of olefins; represent one of the most explored transformations in synthetic …

Vinyl and Alkynyl Triazenes: Synthesis, Reactivity, and Applications

AA Suleymanov, K Severin - Angewandte Chemie, 2021 - Wiley Online Library
Aromatic compounds containing triazenyl groups (N3RR′) have a profound impact on
synthetic organic and medicinal chemistry. In contrast, the chemistry of vinyl and alkynyl …

Spirocyclopropanation Reaction of para-Quinone Methides with Sulfonium Salts: The Synthesis of Spirocyclopropanyl para-Dienones

XZ Zhang, JY Du, YH Deng, WD Chu… - The Journal of …, 2016 - ACS Publications
A novel DBU-mediated stereoselective spirocyclopropanation of para-quinone methides
with sulfonium salts has been developed on the basis of the mode involving a 1, 6-conjugate …

1, 6-Conjugated addition-mediated [2+ 1] annulation: Approach to spiro [2.5] octa-4, 7-dien-6-one

Z Yuan, X Fang, X Li, J Wu, H Yao… - The Journal of Organic …, 2015 - ACS Publications
A formal 1, 6-conjugated addition-mediated [2+ 1] annulation to synthesize spiro [2.5] octa-4,
7-dien-6-one with p-quinone methides and sulfur ylides has been described. This domino …

Enantioselective Spirocyclopropanation of para-Quinone Methides Using Ammonium Ylides

L Roiser, M Waser - Organic letters, 2017 - ACS Publications
The use of Cinchona alkaloid-based chiral ammonium ylides allows for the first highly
enantioselective and broadly applicable spirocyclopropanation reactions of para-quinone …

Generation and utility of cyclic dienyl gold carbene intermediates

C Zhang, K Hong, S Dong, M Liu, M Rudolph… - ACS …, 2023 - ACS Publications
Exploration of intermediates that enable chemo-and stereoselective cycloaddition reactions
for the expeditious construction of fused-and bridged-ring systems continues to draw a great …

Synthesis of spiro [2.5] octa-4, 7-dien-6-one with consecutive quaternary centers via 1, 6-conjugate addition induced dearomatization of para-quinone methides

K Gai, X Fang, X Li, J Xu, X Wu, A Lin… - Chemical …, 2015 - pubs.rsc.org
An efficient one-pot approach for the synthesis of spiro [2.5] octa-4, 7-dien-6-ones by
employing para-quinone methides has been developed. The reaction proceeded smoothly …

Rh(III)-Catalyzed C–H Activation/Cyclization of Benzamides and Diazonaphthalen-2(1H)-ones for Synthesis of Lactones

R Chen, S Cui - Organic letters, 2017 - ACS Publications
A Rh (III)-catalyzed C–H activation/cyclization of benzamides and diazonaphthalen-2 (1 H)-
ones for synthesis of lactones has been developed. In the presence of Rh (III) catalysis, the …

Rhodium (III)-catalyzed C6-selective arylation of 2-pyridones and related heterocycles using quinone diazides: Syntheses of heteroarylated phenols

D Das, P Poddar, S Maity… - The Journal of organic …, 2017 - ACS Publications
An efficient, direct C6-arylation of 2-pyridones has been successfully accomplished with
quinone diazides under Rh (III)-catalyzed redox-neutral conditions. The optimized method is …

Cu (II)-Catalyzed construction of heterobiaryls using 1-diazonaphthoquinones: A general strategy for the synthesis of QUINOX and Related P, N Ligands

A Biswas, S Pan, R Samanta - Organic Letters, 2022 - ACS Publications
An efficient and straightforward method was developed for the synthesis of heterobiaryls
using easily available N-oxides and diazonaphthoquinones under cheap Cu (II) catalysis …